How many moles are in 13grams of C6H6. should this question be broken down into its imperical formula (CH)6 and calculate the number of moles of CH and multiply by 6 or calculate the gram molecular wt of C6H6 and divide it into 13 grams?

moles = grams/molar mass

If you break it down and do units of CH, then multiply by 6 you just do more work to get the same answer you would get if you used the second approach you note.
13/78.11 = ??