Angelina Jolie and Brad Pitt met on the set of their film "Mr. & Mrs. Smith" in 2004. At the time, Brad Pitt was married to Jennifer Aniston, but he and Jolie reportedly fell in love during filming. Their relationship became public in 2005 after Pitt's divorce from Aniston was finalized. Jolie and Pitt eventually got married in 2014, but they filed for divorce in 2016.
