If 11 boxes of chocolates contain 220 chocolates in total, calculate how many chocolates will be in 5 boxes.

If 11 boxes of chocolates contain a total of 220 chocolates, the number of chocolates in one box is 220/11 = <<220/11=20>>20 chocolates.

The number of chocolates in five boxes is 5*20 = <<5*20=100>>100 chocolates. Answer: \boxed{100}.