In the major sources and fate of the following substances in the ruminant digestion.

What was the references and who discovered it?
1) Propionic, ethanoic and butanoic acid
2) Methane
3) Carbon dioxide
4) Ammonia
4

1) Propionic, ethanoic, and butanoic acid: These volatile fatty acids (VFAs) are major end products of carbohydrate fermentation in the rumen of ruminant animals. They are primarily produced by rumen microbes through the breakdown of complex carbohydrates such as cellulose and hemicellulose. The main reference for this topic would be the extensive research conducted on ruminant nutrition and rumen fermentation, which includes studies by various scientists over the years. Some notable contributions to this field include the work of Carl Voelcker, who first characterized the production of VFAs in the rumen in the early 20th century, and subsequent studies by researchers like Desmond J. Kamra, Charles J. Sniffen, and Michael S. Allen.

2) Methane: Methane is a potent greenhouse gas produced by ruminants during digestion. It is primarily generated in the rumen through the process of methanogenesis, which occurs as a result of microbial fermentation of feed carbohydrates in the anaerobic environment of the rumen. Some of the main references for this topic include research papers and studies conducted by scientists like Paul J. Weimer, Terry J. Klopfenstein, Michael S. Allen, and Graeme T. Attwood.

3) Carbon dioxide: Carbon dioxide (CO2) is generated during the fermentation process in the rumen. It is primarily produced as a byproduct of anaerobic microbial metabolism, where carbohydrates are broken down by rumen microbes to produce VFAs. The production and fate of CO2 in ruminant digestion have been extensively studied by researchers such as Michael S. Allen, James B. Russell, David R. Mertens, and Kenneth J. Cheng.

4) Ammonia: Ammonia is a byproduct of protein degradation in the rumen. Proteins from feed sources are subjected to microbial fermentation in the rumen, resulting in the release of ammonia. It is then utilized by rumen microbes as a nitrogen source for the synthesis of microbial protein. The research on ammonia production and utilization in the rumen has been carried out by scientists such as Charles J. Newbold, William R. Houston, and James B. Russell. References for this topic can be found in various research papers and journals on ruminant nutrition and rumen metabolism.