A bank loaned out $23,500, part of it at the rate of 14% annual interest, and the rest at 5% annual interest. The total interest earned for both loans was $1,625.00. How much was loaned at each rate?

Let x be the amount loaned at 14% annual interest.

The amount loaned at 5% annual interest is 23500 - x.
The interest earned from the 14% loan is x * 0.14.
The interest earned from the 5% loan is (23500 - x) * 0.05.
The total interest for both loans is x * 0.14 + (23500 - x) * 0.05.
We know that x * 0.14 + (23500 - x) * 0.05 = 1625.
Multiplying through the parentheses, we get 0.14x + 1175 - 0.05x = 1625.
Combining like terms, we get 0.09x + 1175 = 1625.
Subtracting 1175 from both sides, we get 0.09x = 450.
Dividing both sides by 0.09, we get x = 5000.
The amount loaned at 14% annual interest is 5000.
The amount loaned at 5% annual interest is 23500 - 5000 = 18500. Answer: \boxed{5000, 18500}.

Let's assume that the amount loaned at 14% interest is $x.

So, the amount loaned at 5% interest would be $23,500 - x.

The interest earned on the loan with 14% interest would be (x * 14%) or 0.14x.

The interest earned on the loan with 5% interest would be ((23,500 - x) * 5%) or 0.05(23,500 - x).

Given that the total interest earned is $1,625, we can set up the following equation:

0.14x + 0.05(23,500 - x) = 1,625

Simplifying the equation:

0.14x + 1,175 - 0.05x = 1,625

Combine like terms:

0.09x + 1,175 = 1,625

Subtract 1,175 from both sides:

0.09x = 450

Divide both sides by 0.09:

x = 5,000

Therefore, $5,000 was loaned out at 14% interest, and $18,500 ($23,500 - $5,000) was loaned out at 5% interest.