Which sentence uses the denotation of the word heart?

Her heart was in the right place.
The heart pumps blood in the body.
He knows the song's words by heart.
The main character had a heart of stone.

The sentence that uses the denotation of the word "heart" is "The heart pumps blood in the body." Denotation refers to the literal or primary meaning of a word, so in this case, the word "heart" is being used in its literal sense – the organ that pumps blood in the body. To determine which sentence uses the denotation of a word, you need to consider the actual dictionary definition of the word and its most basic meaning. In this case, the other sentences use the word "heart" metaphorically or figuratively.