why is C4H10 the simplest alkane that can have structural isomers?

To understand why C4H10 (butane) is the simplest alkane with structural isomers, we need to know what structural isomers are and the concept of alkane hydrocarbons.

Alkanes are a type of hydrocarbon—a compound consisting of only hydrogen (H) and carbon (C) atoms. They follow the general formula CnH2n+2, where "n" represents the number of carbon atoms. Alkanes are known for their straight or branched chain structure, with carbon atoms bonded to each other and hydrogen atoms.

A structural isomer is a compound that has the same molecular formula but differs in the arrangement of atoms within the molecule. This means that structural isomers have different connectivity between their atoms, resulting in different physical and chemical properties.

Now, let's discuss why C4H10 (butane) is the simplest alkane with structural isomers:

In the case of alkanes, structural isomerism occurs when carbon atoms are arranged differently. For C4H10, we have four carbon atoms. Let's explore the possible arrangements:

1. Straight-chain butane: In this arrangement, all four carbon atoms form a continuous, unbranched chain. This is the most commonly known form of butane.

2. Branched-chain butane: Here, three carbon atoms form the longest continuous chain, and the fourth carbon atom branches off from the middle. This creates a branched structure.

Hence, C4H10 has two structural isomers: straight-chain butane and branched-chain butane. The straight-chain form has a linear shape, while the branched-chain form has a non-linear shape due to the branching carbon atom.

Overall, C4H10 is the simplest alkane to have structural isomers because it has a sufficient number of carbons (four) to allow for different arrangements while still maintaining the molecular formula, C4H10.