# Chemistry

posted by Anonymous

Consider the titration of 50.0 mL of 0.20 M NH3 (Kb = 1.8x10^-5) with 0.20 M HNO3. Calculate the pH after addition of 50.0 mL of the titrant.

1. DrBob222

The secret to doing titration problems is to recognize what you have in the solution. In this case, the NH3 is exactly neutralized by the HNO3; therefore, you are at the equivalence point and you have NH4NO3 is solution. How much NH4NO3? That will be 50.0 mL x 0.20 M = 10 millimoles in 100 mL = 0.1 M

Write the hydrolysis equation.
NH4^+ + HOH ==> NH3 + H3O^+
Then do the ICE bit.
Ka = Kw/Kb = (NH3)(H3O^+)/(NH4^+
Solve for (H3O^+) and convert to pH.

2. alyx

5.13

3. Gelagay Tekalign

8.5

## Similar Questions

1. ### anaytical chemistry

experiment: potentiomeric titration 1. Why is continuos stirring (use of stirrer and magnetic stir bar)important in potentiometric titration?
2. ### college

Consider the titration of 50.0 mL of 0.20 M NH3 (Kb=1.8*10^-5) with 0.20 M HNO3. Calculate the pH after addition of 50.0 mL of the titrant.
3. ### chem

A 75.0 mL volume of 0.200 M NH3 (Kb=1.8x10^-5) is titrated with 0.500 M HNO3. Calculate the pH after the addition of 28.0 mL of HNO3.
4. ### chem

A 75.0 mL volume of 0.200 M NH3 (Kb=1.8x10^-5) is titrated with 0.500 M HNO3. Calculate the pH after the addition of 28.0 mL of HNO3.
5. ### chem

Consider the titration of 30.0 mL of 0.050 M NH3 with 0.025 M HCl. Calculate the pH after the following volumes of titrant have been added. (The Kb for NH3 is 1.8e-05.) (a) 0 mL . (b) 25.0 mL . (c) 59.0 mL . (d) 60.0 mL (e) 63.0 mL …
6. ### chemistry college

Consider the titration of 30.0 mL sample of 0.050 M NH3 with 0.025 M HCl. Calculate the pH after the following volumes of titrant (acid)have been added: a)0 mL, b)20.0mL, c)60.0mL, d)65mL Kb for NH3 is 1.8 x 10^-5
7. ### Chem

A 75.0 mL volume of 0.200 M NH3 (Kb=1.8x10^-5) is titrated with 0.500 M HNO3. Calculate the pH after the addition of 28.0 mL of HNO3.
8. ### Chemistry

Consider the titration of 30.0 mL of 0.100 M NH3 with 0.150 M HCl. calculate the pH after the following volumes of titrant have been added:(a) 0mL (b) 10.0 mL (c) 19.5 mL (d) 20.0 mL (e) 20.5 mL (f) 30 mL
9. ### chemistry

Calculate the pH values and draw the titration curve for the titration of 500 mL of 0.010 M acetic acid (pKa 4.76) with 0.010 MKOH. Calculate the pH of the solution after 490 mL of the titrant have been added. Calculate the pH of the …
10. ### chemistry

Calculate the pH values and draw the titration curve for the titration of 500 mL of 0.010 M acetic acid (pKa 4.76) with 0.010 MKOH. Calculate the pH of the solution after 490 mL of the titrant have been added. Calculate the pH of the …

More Similar Questions