how do you identify an anode and cathode by direct observation in an electochemical battery when you don't have a voltmeter and the chemicals are no known.

I look on the battery for a + and - sign. In a battery, the + pole is the cathode and the - pole is the anode.

If you do not have a voltmeter and the chemicals in the battery are not known, it can be a bit trickier to identify the anode and cathode directly. However, there are a few ways you can still make an educated guess:

1. Size and shape: In some batteries, the anode and cathode may be physically different in size or shape. Generally, the cathode is larger and flatter, while the anode is smaller and more cylindrical in shape. However, this is not always the case and can vary depending on the specific battery design.

2. Labeling or color coding: Check for any labels or color coding on the battery. Some batteries may have a + (plus) sign or a color code like red to indicate the positive (cathode) terminal, while the - (minus) sign or a color code like black may indicate the negative (anode) terminal. However, not all batteries have these markings.

3. Terminal configuration: In some batteries, the terminal configuration can hint at the anode and cathode. Often, the cathode terminal is the one that is connected to the positive side of the battery, while the anode terminal is connected to the negative side. However, this is not always the case, especially in certain specialized battery designs.

Keep in mind that these methods are not foolproof and may not always provide a definitive answer. If you want to be absolutely certain about the anode and cathode without using a voltmeter, you may have to conduct further research on the specific battery model or consult the manufacturer's documentation.