Does hydrogen fluoride form hydrogen bonds between itself and water?

Yes, hydrogen fluoride (HF) can form hydrogen bonds with water (H2O). Hydrogen bonding occurs when there is a strong dipole-dipole attraction between a hydrogen atom, which is bonded to a highly electronegative atom (like fluorine, oxygen, or nitrogen), and another electronegative atom with a lone pair of electrons.

In the case of HF interacting with H2O, the hydrogen atom of HF, which is partially positively charged due to the high electronegativity of fluorine, can form a hydrogen bond with the lone pair of electrons on the oxygen atom of a water molecule. Conversely, the hydrogens of the water molecule can also engage in hydrogen bonding with the lone pairs on the fluorine atom of HF.

This ability to form hydrogen bonds with water makes HF highly soluble in water, leading to the formation of a solution known as hydrofluoric acid, which is a weak acid but highly corrosive due to its ability to react with silica and other substances.