In which scenario is the experimental probability equal to the theoretical probability?

A coin is flipped six times and the head appears each time.

A coin is flipped six times and the head appears three times.

A coin is flipped six times and the head appears five times.

A coin is flipped six times and the head appears four times.

None of the scenarios listed has experimental probability equal to theoretical probability, as the theoretical probability of flipping heads on a fair coin is always 0.5. The experimental probability may approach 0.5 with a large number of trials, but it will never be exact.