Consider the electronic configuration of an atom:

A.what are the n, l and ml quantum numbers corresponding to the 3s orbital?

B.List all the possible quantum numbers values for an orbital in the 5f subshell?

You can figure this out if you know the rules.

n can be any whole number beginning with 1.
l can be any whole number from 0 to n-1.
ml can be any whole number from -l to +l including 0.
ms can be +1/2 or -1/2.

Answer

To determine the quantum numbers corresponding to a specific orbital, we need to understand the rules and principles governing quantum mechanics.

A. To find the quantum numbers for the 3s orbital:

1. The principal quantum number (n) represents the energy level or shell of the electron. In this case, since we are considering the 3s orbital, the principal quantum number (n) is 3.

2. The azimuthal quantum number (l) indicates the shape of the orbital. For an s orbital, l is always equal to 0.

3. The magnetic quantum number (ml) specifies the orientation of the orbital in space. For the 3s orbital, ml can have only one value, which is 0.

So, for the 3s orbital:
n = 3
l = 0
ml = 0

B. To determine the possible quantum number values for the 5f subshell:

1. The principal quantum number (n) is 5, as we are considering the 5f subshell.

2. The azimuthal quantum number (l) can have values ranging from 0 to n-1. Therefore, l can be 0, 1, 2, 3, or 4 for the 5f subshell.

3. The magnetic quantum number (ml) can have values ranging from -l to +l. Therefore, for each possible value of l, ml can take all the integers in the range from -l to +l.

So, for the 5f subshell, the possible quantum number values are:
n = 5
l = 0, 1, 2, 3, 4
ml = -l, (-l+1), (-l+2), ..., (l-1), l

Note that each combination of n, l, and ml represents a unique orbital within the subshell.