Consider compounds trans-4-tert-butylcyclohexanol and 4-tert-butylcyclohexanone below. Using silica gel TLC plates, which of these two compounds will have the higher Rf value when dichloromethane is the developing solvent?

163,075 results

  1. Chemistry

    Consider compounds trans-4-tert-butylcyclohexanol and 4-tert-butylcyclohexanone below. Using silica gel TLC plates, which of these two compounds will have the higher Rf value when dichloromethane is the developing solvent? Why? Does it possibly have to do with the polarity?
  2. Chemistry

    Consider the compounds 4-tert-butylcyclohexanol and 4-tert-butylcyclohexanone. Using silica gel plates, which of the two compounds will have the higher Rf value when ethyl acetate is the developing solvent? Which will have the higher Rf value when dichloromethane is the ...
  3. Organic Chemistry

    The compounds below are contained in a mixed sample. Rank the compounds in order of elitism if separated using a silica gel column rank them from what elutes first to what elutes last. Benzoic acid, 1,3-dichlorobenzene, tert-butylcyclohexane, and 2-pentanol So far from first ...
  4. Chemistry

    suppose you carry out a TLC separation of acetaminophen and phenacetin on silica gel using a non polar developing solvent. which should have a higher Rf value, and why?
  5. Chemistry

    Arrange the following compounds in order of decreasing ease of elution from a column of silica gel: a) 2-octanol; b) 1,3-dichlorobenzene; c) tert-butylcyclohexane; d) benzoic acid
  6. Chemistry

    Arrange the following compounds in order of decreasing ease of elution from a column of silica gel: a) 2-octanol; b) 1,3-dichlorobenzene; c) tert-butylcyclohexane; d) benzoic acid
  7. CHemistry

    Arrange the following compounds in order of decreasing ease of elution from a column of silica gel: a) 2-octanol; b) 1,3-dichlorobenzene; c) tert-butylcyclohexane; d) benzoic acid I was wondering if this was the correct order of it: Tert-butylcyclohexane > 1,3-...
  8. chemistry

    -Suppose you carry out TLC separation of acetaminophen and ibuprofen on silica ggel using a nonpolaar developing solvent. which should have a higher Rf? -Assuming that the drug components whose spots you identified dissolved completely when you stirred the tablet with 1:1 ...
  9. Chemistry

    Why use Methyl tert-butyl ether in the organic chemistry lab when separating compounds? separating WHAT compounds and how? as a solvent? It has a low boiling point and isn't very reactive, generally, but there may be other specific reasons depending upon the compounds being ...
  10. Science

    When 2-propanol was used as the developing solvent, two substances moved with the solvent front (Rf = 1) during TLC analysis on a silica gel plate. Can you conclude that they are identical? If not, what additional experiment would you perform?
  11. organic chemistry

    when 2 propanol was used as the developing solvent, two substances moved with the solvent front (Rf=1) during TLC analysis on a silica gel plate. can you conclude that they are identical? if not what additional experiments would you perform?
  12. Chemistry

    A student needs to analyze a mixture containing an alcohol and a ketone by silica gel tlc. Consult the table of solvent polarities above and suggest a likely developing solvent. Explain
  13. Organic Chem Lab

    If I have separate solutions of the compounds benzoic acid and benzaldehyde, and they are spotted on an alumina gel TLC plate and run using CH2Cl2 as the eluant, which compound will have the higher Rf value? Explain.
  14. Chemistry

    Assume your sample spots are 1 cm above the bottom of the TLC plate. What happens if you put the plate in a developing chamber that has 1.2 cm of developing solvent? A. The solvent will move up the plate by capillary action faster. B. The sample spots will become more ...
  15. Chem---DrBob222

    -----Chromatograph----- Carrying out TLC on colorless compounds. Give two examples of methods to use in order to visualize the spots on the plates. Carrying out TLC with a mixture of two compounds A and B. A is less polar than B. on a reverse phase plate which compound would ...
  16. Chemistry Check

    Just want to make sure that my thought process is right on this one. 5 compounds: n-butyl chloride n-butyl bromide sec-butyl chloride tert-butyl chloride and crotyl chloride Each is reacted with NaI (SN2?) and AgNO3 (SN1?) And we have to rank the reaction time and wether we ...
  17. science(chem)

    Consider the following errors that could be made when running the TLC. Indicate what should be done to correct the error. a) A 2 component mixture containing 1-octene and 1,4- dimethylbenzene gave only 1 spot with and Rf value of 0.95. The solvent used was acetone b) A 2 ...
  18. TLC error correction

    Question: Consider the following errors that could be made when running TLC. Indicate what should be done to correct the error. A. A two-component mixture containing 1-octene and 1,4-dimethylbenzene gave only one spot with an Rf value of 0.95. The solvent used was acetone. In ...
  19. Chemistry

    Choccamine and mintanol have Rf values of 0.81 and 0.21 respectively. What would the distance in centimetres (cm) between the two compounds be if the TLC was run on a TLC plate where the solvent front moved 8.9 cm from the baseline?
  20. Chemistry

    Below is the question I am trying to answer. I think after much debate, I may have it. Does anyone know if I am close to being right? Does cis and trans isomeric compounds display different properties? Why? Cis means on the same side and trans means on the opposite side. Cis ...
  21. Chemistry

    Below is the question I am trying to answer. I think after much debate, I may have it. Does anyone know if I am close to being right? Does cis and trans isomeric compounds display different properties? Why? Cis means on the same side and trans means on the opposite side. Cis ...
  22. Lab conclusion- HELP!

    I' am currently trying to wrie a couple of lab conclusions and having a hard time coming up with good points to make for the following lab experiment: Thin layer chorotography If anyone has a few minutes to give me a couple tips on how to improve this. I think it sounds like a...
  23. Identical compounds?

    Question: You and another student were each given an unknown compound. Both samples contained colorless material. You each used the same brand of commercially prepared TLC plate and developed the plates using the same solvent. Each of you obtained a single spot of Rf = 0.75. ...
  24. Chemistry

    You carry out tlc on silica gel of a mixture of compound A and B. Using a mobile phase of hexane 50% and acetone 50% the Rf values of were A 0.15, B 0.2, and the spots were overlapping. What change would you make to the solvent composition to improve the separation? Explain.
  25. Difference?

    What is the difference between these two questions? They look the same to me, like they're asking the same thing. Not likely. Question: A student spots an unknown sample on a TLC plate and develops it in dichloromethane solvent. Only one spot, for which the Rf value is 0.95, ...
  26. TLC purity

    Question: A student spots an unknown sample on a TLC plate and develops it in dichloromethane solvent. Only one spot, for which the Rf value is 0.95, is observed. Does this indicate that the unknown material is a pure compound? What can be done to verify the purity of the ...
  27. chemistry

    Consider a set of compounds called carboxylic acids which have the general formula CH3(CH2)nCO2H. As the value of n in the formula increases from zero to 10, what happens to the solubility of these compounds in water? What happens to the compounds solubility in carbon ...
  28. organic chemistry

    How will i know if the r group's common name is tert-pentyl or sec-penytl? What is the difference between sec and tert?
  29. Rf values

    Question: Consider a sample that is a mixture composed of biphenyl, benzoic acid and benzyl alcohol. The sample is spotted on a TLC plate and developed in a dichloromethane-cyclobutane solvent mixture. Predict the relative Rf values for the three components in the mixture. (...
  30. organic chemistry

    1if you open the tert-butyl chloride and tert-butyl bromide to the air for few hours? What happened to the ratio of the halide mixture during this time? (2-methyl-2-propanol reaction )
  31. chem

    The Rf value of compound A is .34 when the TLC plate is developed in hexane and .44 when the plate is developed in diethyl ether. Compound B has an Rf value of .42 in hexane and .60 in diethyl ether. Which solvent would be better for seperating a mixture of compounds A and B ...
  32. chemistry

    Suggest a solvent pair for N-Bromosuccinimide using the following solubility data. Solubility of N-Bromosuccinimide (g/100g of solvent) Tert-butanol 0.73 Hexane 0.006 Glacial acetic acid 3.10 Acetone 14.40 Carbon tetrachloride 0.02
  33. Organic Chemistry

    I spotted a commercial TLC plate, coated with silica gel, with a pure benzoin solution. After running the TLC plate in methylene chloride, the benzoin separated into two different spots. Rf values are 0.6 and 0.9. What explains this? A pure material should have only one spot ...
  34. chemistry another Q

    Which, 9-fluorenol or 9-fluorenone, would have higher Rf value on a silica gel plate with 30% acetone/70% hexane at the eluent? Explain.
  35. Chemistry

    Consider the following errors that could be made when running TLC. Indicate what should be done to correct the error. a) a two-component mixture containing 1-octene and 1,4-dimethylbenzene gave only one spot with an Rf value of .95. The solvent uses was acetone. b) a two-...
  36. Chemistry/ OChem

    Consider the following errors that could be made when running TLC. Indicate what should be done to correct the error. a) a two-component mixture containing 1-octene and 1,4-dimethylbenzene gave only one spot with an Rf value of .95. The solvent uses was acetone. b) a two-...
  37. gr 12 chemistry

    consider the two compounds, CH3CH2CH2CH2CH2OH and CH3CH2OCH2CH2CH3. Giving reasons for your choice, select the compound that a) will evaporate at a lower temperature b) has higher solubility in a non-polar solvent c) can undergo an addition reaction with hydrogen
  38. Chemistry

    You and another student were each given an unknown compound. Both samples contained colorless material. You each used the same brand of commercially prepared TLC plate and developed the plates using the same solvent. Each of you obtained a single spot of Rf=0.75. Were the two ...
  39. Chemistry

    Consider the following errors that could be made when running TLC. Indicate what should be done to correct the error. a) a two-component mixture containing 1-octene and 1,4-dimethylbenzene gave only one spot with an Rf value of .95. The solvent uses was acetone. b) a two-...
  40. organic chemistry lab pLEASE HELP

    Which, 9-fluorenol or 9-fluorenone, would have higher Rf value on a silica gel place with 30% acetone/70% hexane as the eluent? Explain.
  41. science(chemistry)

    I have a question about solvent evaporation. If I had an organic layer and an aqueous layer in an unknown mixture of liquids and wanted to obtain the solid of a compound(s) dissolved in the layers, is it reasonable to assume that I can run the compound in the IR spectrometer (...
  42. chemistry

    1. You are given a mixture containing two compounds, A and B. Both compounds have a solubility of 1 g/ 100 mL of solvent at 20 °C and 16 g/ 100 mL of solvent at 100 °C. The sample is composed of 3.5 g of A and 10 g of B. At 100 °C the entire sample just dissolves in a ...
  43. organic chemistry

    isobutyl tert pentyl acetylene has how many hyrogen atoms? iso=2 butyl=4 tert=4 pentyl=5 acetylene=2 28 h atoms? can you please teach me how to compute hydrogen atoms.. Neoheptane has how many atoms?
  44. organic chemistry

    a careless organic chemistry student was performing "competing nucleophiles in nucleophilic substitution reactions" experiment , and left his container of tert-butyl chloride and tert-butyl bromide open to the air for several hours. what happened to the composition of the ...
  45. chemistry

    How can you tell which mobile phase is more polar in TLC? (hexane/ethyl acetate/ethanol vs. isopropanol/ammonia)? the hexane/ethyl acetate/ethanol travelled up the TLC faster, does this make it more polar? The TLC is silica gel!
  46. chemistry

    help please, have no clue how to solve this. (a) you are given a mixture containing two compounds, A and B. both compounds have a solubility of 1g/100mL of solvent at 20 deg C and 16g/100mL of solvent at 100 deg C. The sample is composed of 3.5 g of A and 10 g of B. at 100 deg...
  47. Chemistry

    A sample of plant extract is subjected to thin layer chromatography using aluminum backed plates of 0.25 mm thickness. The sample extract is suspected to contain a series of related compounds with hydroxyl and ester functional groups. Suggest a suitable solvent or solvent ...
  48. chemistry

    see if on tlc silica if the polar solvent moves slowly then does even polar substances rf value is low? and the nonpolar rf is high?
  49. Science - Chromatography

    I performed a TLC of plant pigments in my lab class with a solvent of petroleum ether/ acetone (7:3) and used a silica gel plate. It is expected that the most polar pigments (chlorophyll) will be located near the bottom and the carotenoids near top. In my experiment, it was ...
  50. chemistry

    What is a special group of compounds that produce H+ ions when dissolved in water? A. Acids B. Ionic compounds C. Molecular compounds D. Polyatomic compounds I think A
  51. chemistry

    What is the order that these four compounds would travel through a silica gel column during liquid chromatography? a) ethylene glycol, HOCH2CH2OH b) aqueous sodium chloride solution, NaCl (aq) c) propanol, CH3CH2CH2OH d) benzene, C6H6 (eluted first), ???, ???, ???, ??? (eluted...
  52. Chemistry-Paramagnetic or Diamagnetic

    I did a lab where I was supposed to make "estimates" on transition compounds based on their electron configuration of how the compounds will react positively or negatively and then to experiment the compounds in conjunction with the strong magnets to evaluate their ...
  53. Organic Chemistry

    Because alcohol protons are reasonably acidic and easily undergo exchange, it is important that the base be matched to the appropriate solvent. Explain why it would be virtually impossible to sort out the factors the size of the base or the stability of the alkenes formed if a...
  54. organic chemistry

    Because alcohol protons are reasonably acidic and easily undergo exchange, it is important that the base be matched to the appropriate solvent. Explain why it would be virtually impossible to sort out the factors the size of the base or the stability of the alkenes formed if a...
  55. Chemistry

    Is it even possible to guess the signs of Delta H, S, and G from only knowing the following information?: - Silica gel is a solid. - Chemically inert. - Highly porous. - Amorphous form of SiO2. - Water vapor is absorbed onto the surface of silica gel and acts as a desiccant to...
  56. science(chem)

    [b]1.[/b]Is TLC a qualitative or quantitative analysis? Is there any way that it can be both? Explain. ~I say it can be both since it can be used to go and determine what exactly is in a sample of mixed compounds which would be qualitative analysis. It can also be quantitative...
  57. chem

    Two gas tanks containing compounds A and B are connected by separate valves to two ends of a 10 meter glass tube as shown below. When both valves are thrown open at the same time A and B travel down the tubes towards each other. A white line appears when they meet and b has ...
  58. CHemistry....Please help

    1.SOLUBILITY: At 25C, the molar solubility of calcium phosphate in water is 1.1*10^{-7}M. Calculate the solubility in grams per liter. I m not sure how to convert M to g/L MOLAR MASS OF COLLIGATIVE PROPERTIES: 2.tert-Butyl alcohol is a solvent with a Kf of 9.10 C/m and a ...
  59. TLC

    The following two solvents systems were found to separate compounds x and y by flash column chromatography: X- hexanes/ethyl acetate 10:1 Y- hexanes/ethyl acetate 10:4 which is more polar X or Y? Which solvent system must be used first?
  60. chemistry

    Which of the following statements concerning differences between ionic and molecular compounds is correct? Molecular compounds contains two elements, and ionic compounds contain three of more elements ionic compounds contain oxygen, and molecular compounds do not. molecular ...
  61. science (chem)

    consider a sample that is a mixture of biphenyl, benzoic acid, and benzyl alchohol. The sample is spotted on a TLC plate and developed in a methylene chloride cyclohexane mixture. Predict the relative Rf values for the three components in the sample. For assistance use the ...
  62. Chemistry-help needed

    I have a question on thin layer chromatography (TLC). My mobile phase (i.e. developing solvent) is a mixture of 2 non-polar solvents. After preparing the mobile phase, is it necessary to pour some into the developing chamber to saturate the chamber or should we only pour the ...
  63. science (chem) Rf values

    consider a sample that is a mixture of biphenyl, benzoic acid, and benzyl alchohol. The sample is spotted on a TLC plate and developed in a methylene chloride cyclohexane mixture. Predict the relative Rf values for the three components in the sample. For assistance use the ...
  64. Organic Chemistry

    The separation of a mixture of benzoic acid and benzoin in dichloromethane into its pure compounds by a combination of solvent extraction , distillation and recrystallization. Why is carbon dioxide evolved when the organic solution is shaken with sodium bicarbonate? what is ...
  65. Chemistry-thanks

    I have a method using HPLC (high performance liquid chromatography). It states that a 4.6 x 150mm,3um column should be used. (stationary phase : octadecylsilyl silica gel). I have a 4.6 x 100mm,2.7um column, silica-based, bonded-phase (non-polar) column. Can you advise if ...
  66. Chem

    Sort the pairs of related compounds by their carbonyl stretching frequencies in cm–1. (There will be three compounds per bin.) Bin # 1: Slightly higher Bin #2: Slightly lower Compounds: -butanol -but-2-enal -heptan-3-one -hept-4-en-3-one -cinnamaldehyde -3 phenylpropanal
  67. Dr. Bob please help :)

    Sort the pairs of related compounds by their carbonyl stretching frequencies in cm–1. (There will be three compounds per bin.) Bin # 1: Slightly higher Bin #2: Slightly lower Compounds: -butanol -but-2-enal -heptan-3-one -hept-4-en-3-one -cinnamaldehyde -3 phenylpropanal
  68. chemistry

    ionic componuds tend to have higher boiling points than covalent compounds . both ammonia NH3 and methane CH4 are covalent compounds but yet the boiling point of ammonia 130C is higher than methane. what might account for this difference please help thank you
  69. PLEASE HELP CHEM DR BOB :O

    Sort the pairs of related compounds by their carbonyl stretching frequencies in cm–1. (There will be three compounds per bin.) Bin # 1: Slightly higher Bin #2: Slightly lower Compounds: -butanol -but-2-enal -heptan-3-one -hept-4-en-3-one -cinnamaldehyde -3 phenylpropanal
  70. CHEMISTRY

    list three differences between molecular and ionic compounds, and explain how they relate to the differences in bond types.....how do i relate to the differences in bond types? List the differences and we'll talk about how they relate to the bond type. 1. molecular compounds ...
  71. Interactions

    Question: Interactions: Summarize this section (in the book) in your own words and for each interaction give a complete sentence. The strength of interactions of eluted compounds with alumina or silica gel depends on how strongly they are adsorbed to the adsorbants. I will ...
  72. organic chem

    An unknown compound melted at 131-133°C. It is thought to be one of the following compounds(mp,°C): trans-cinnamic acid (133-134); benzamide(128-130); DL-malic acid(131-133); or benzoin(135-137). The mixture melting points of the unknown compound with each of the test ...
  73. Chem

    Consider the reduction of 4-t-butylcyclohexanone. If the procedure calls for 153 mg of 4-t-butylcyclohexanone, what mass of sodium borohydride should be added?
  74. Chemistry

    Consider the reduction of 4-t-butylcyclohexanone. If the procedure calls for 153 mg of 4-t-butylcyclohexanone, what mass of sodium borohydride should be added?
  75. Physics

    What kind (s) of particles make up (a) gaseous compounds, (b) liquid compounds, and (c) solid compounds?
  76. chemistry

    One afternoon, a graduate student set up a silica gel column to chromatograph a mixture of two colourless products whose Rf values were quite close. Suddenly, he realized that he had tickets to the Leafs game that night. He turned the stopcock to stop collecting eluent, put a ...
  77. chemistry

    Two compounds of molecular formula respectively C2H4O and C4H8O produce a yellow orange precipitate by the reaction DNPH. a)is this indication sufficient to write the structural formulas of these two compounds? Explain. b)what identification tests should further be done to ...
  78. Chemistry-help needed

    Posted by angie on Saturday, October 8, 2011 at 6:02am. I have a method using HPLC (high performance liquid chromatography). It states that a 4.6 x 150mm,3um column should be used. (stationary phase : octadecylsilyl silica gel). I have a 4.6 x 100mm,2.7um column, silica-based...
  79. DR BOB PLEASE HELP CHEM

    Consider the reduction of 4-t-butylcyclohexanone. If the procedure calls for 153 mg of 4-t-butylcyclohexanone, what mass of sodium borohydride should be added?
  80. science(chem)

    statement from my text says: "like disolves like", This rule is most commonly applied to polar and nonpolar compounds. According to this rule, a polar solvent will dissolve polar(or ionic) compounds and non polar solven will dissolve nonpolar compounds. For this statement I ...
  81. Chem Help Please!

    You are carryingout TLC on normal phase plates. Compound A has an Rf of 0.4 and compound B of 0.6. What would happen to the Rf values if you increase the polarity of the mobile phase? For the compounds in question 1, you change to running them on reverse phase plates. What ...
  82. Chem Help Please!

    You are carryingout TLC on normal phase plates. Compound A has an Rf of 0.4 and compound B of 0.6. What would happen to the Rf values if you increase the polarity of the mobile phase? For the compounds in question 1, you change to running them on reverse phase plates. What ...
  83. science(chemistry)

    I have a question about TLC plate solvents. What solvents will leave stains on a plate with a TLC plate out of the ones below and why?) (n-Octane, n-Hexane, Decane, Acetone, 1-Propanol, 2-Propanol, Ethanol, Toluene, Cyclohexane, Methanol, n-Heptane, n-Pentane, Butanol) I saw 2...
  84. CHEMistry

    A mixture of two compounds, A and B, was separated by extraction. After the compounds were dried, their masses were found to be: 117 mg of compound A and 91 mg of compound B. Both compounds were recrystallized and weighed again. After recrystallization, the mass of compound A ...
  85. chemistry

    what are 4 chemical properties of organic compounds?i know there non polar molecules and they tend to e soluble in non polar solvents,,but my homework says i need 2 more and i don't know what else..thanks :) Some organic compounds are non-polar and some are polar. In fact, ...
  86. Chemistry!!!

    1.)The silica that makes up the stationary phase in TLC chromatophraphy is more polar than the mobile phase. What then might the relative positions of the analgesics on the developed TLC plate tell you about the polarity of these molecules? Does this match the expectations ...
  87. chemistry

    Which solvent would dissolve each of the following compounds?(water, a polar organic solvent, or a nonpolar organic solvent) a) NaI b) H3CCH2CH2OH C)H3CCH2CH2CH2CH2CH2CH2CH3
  88. Science

    Table salt has the chemical formula NaCl. Table sugar has the chemical formula C12H22O11. Which of the following is true? (1 point) Both compounds are held together by chemical bonds. Both compounds have the same density. Both compounds react with water. Both compounds contain...
  89. Science

    Table salt has the chemical formula NaCl. Table sugar has the chemical formula C12H22O11. Which of the following is true? (1 point) Both compounds are held together by chemical bonds. Both compounds have the same density. Both compounds react with water. Both compounds contain...
  90. Science

    Plz Correct me!! Table salt has the chemical formula NaCl. Table sugar has the chemical formula C12H22O11. Which of the following is true? (1 point) Both compounds are held together by chemical bonds. Both compounds have the same density. Both compounds react with water. Both ...
  91. Chemistry

    Explain why the melting points of ionic compounds and molecular compounds differ? The melting points of ionic compounds and molecular compounds differ because.... -A tremendous amount of energy (heat transfer) is required to separate the tightly bound ions in solid ionic ...
  92. chemistry

    Why do compounds with strong intermolecular attractive forces have higher boiling points than compounds with weak intermolecular attractive forces?
  93. chemistry

    For a TLC lab,the stationary phase is the mixture of isopropanol and ammonia or the mixture of hexane,ethyl acetate and ethanol, the stationary phase is silica gel. text some dyes and drugs. what is the relationship between the polarity of molecules and the Rf values?
  94. chemistry

    Picking any two compounds, how do you describe which one has a higher dispersion force using the words Larger electron cloud and polarizability? Thanks:)
  95. physics

    why do chemical compounds tend to dissolve more quickly in hot solvent than in cold solvent?
  96. science

    Which of the following is NOT true about compounds? A) compounds join in specific ratios according to their masses B) the mass ratio of a specific compound is always the same C) compounds are random combinations of elements D) different mass ratio mean different compounds
  97. chemistry

    For a TLC lab,the stationary phase is the mixture of isopropanol and ammonia or the mixture of hexane,ethyl acetate and ethanol, the stationary phase is silica gel. text some dyes and drugs. which one of the two mobile phases is the more polar? Actualy I need two pieces of ...
  98. Chemistry

    what are two general properties of molecular compounds? Generally they are soft and have a low melting point (when compared to ionic compounds). There are exceptions, of course. For exmaple, diamond is not soft.
  99. chemistry

    In TLC, why do you spot multiple times? Select one or more correct answers. A. To fill the capillary almost instantly by capillary action. B. So the developing chamber solvent does not evaporate. C. The higher compound concentration facilitates visualization. D. To acheive a ...
  100. Org. Chem.

    Synthesize 6-(4-tert-butylphenyl)cyclohex-3-enecarbonitrile using (Z)-3-phenylacrylonitrile as your starting material and any other reagents you wish. Please help and an explanation would be greatly appreciated.
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