if 50cm3 of co3 were put in 40cm3 of O2. Determine the gas that would be in excess and calculate the volume of gas that would be unused

To determine which gas is in excess and calculate the volume of gas that would be unused, we need to compare the stoichiometric ratio of the two gases involved in the reaction.

Since we are given the volumes of the gases, we'll need to use the ideal gas law to convert them to moles before comparing their ratios. The ideal gas law equation is:

PV = nRT

Where:
P = pressure (assume constant for this calculation)
V = volume of gas
n = number of moles
R = ideal gas constant
T = temperature (assume constant for this calculation)

Given:
Volume of CO2 (V1) = 50 cm^3
Volume of O2 (V2) = 40 cm^3

Let's convert the volumes to moles by using the equation:

n = PV / RT

Assuming the pressure, temperature, and gas constants are the same for both gases, we can compare the number of moles of CO2 (n1) to the number of moles of O2 (n2) to find the excess gas.

n1 = (P * V1) / RT
n2 = (P * V2) / RT

Once we determine the excess gas, we can calculate the volume of the gas that would be unused.

If n1 > n2, then CO2 is in excess:
Excess volume = V1 - (n2 * RT / P)
Unused volume = V2

If n2 > n1, then O2 is in excess:
Excess volume = V2 - (n1 * RT / P)
Unused volume = V1

If n1 = n2, then both are used up, and the unused volume is 0.

Remember, to completely determine the excess gas and unused volume accurately, we would need the values of pressure (P) and temperature (T) of the gases involved.