4.69 of S is reaction with oxygen calculate the volume of SO2 in mL formed at 33 degrees C and 1.14 atm

Write the equation and balance it.

Convert 4.69g S to mols. mols = grams/molar mass.
Convert mols S to mols SO2 by using the coefficients in the balanced equation.
Then use PV = nRT to convert mols to volume(in liters) and convert that to mL.