Is NH4+ a polar or nonpolar bond?

The NH4+ ion, also known as the ammonium ion, has a polar bond. This is because the nitrogen atom (N) has a greater electronegativity than the hydrogen atoms (H), resulting in an uneven distribution of electron density. The nitrogen atom pulls the shared electrons closer, giving it a partial negative charge, while the hydrogen atoms have a partial positive charge. Therefore, NH4+ is a polar molecule.

To determine whether NH4+ (ammonium ion) has a polar or nonpolar bond, we need to consider the polarity of the individual bonds and the molecular geometry.

The NH4+ ion consists of four hydrogen (H) atoms covalently bonded to a central nitrogen (N) atom. Nitrogen has five valence electrons, while hydrogen has one valence electron each. Therefore, nitrogen shares one electron with each hydrogen atom, resulting in four covalent bonds.

Now, let's examine the molecular geometry of NH4+. The four hydrogen atoms are arranged in a tetrahedral shape around the central nitrogen atom. Since the four H atoms occupy the four corners of the tetrahedron, the molecular geometry can be described as tetrahedral.

Each nitrogen-hydrogen bond is polar, meaning there is a partial positive charge on hydrogen and a partial negative charge on nitrogen. This polarity arises from the difference in electronegativity between nitrogen and hydrogen. Nitrogen is more electronegative than hydrogen, causing it to pull the shared electrons towards itself, resulting in a partial negative charge.

Considering that NH4+ has a tetrahedral molecular geometry and polar bonds, we can conclude that the molecule is polar overall. The lone pairs on nitrogen also contribute to the polarity of the molecule.

Each N-H bond is polar because N and H don't have the same electronegativity. H is about 2.1 and N is about 3.0. So I would classify each of the 4 N-H bonds as polar covalent. A related question is does NH4^+ have a dipole moment due to the polar bonds. No, it does not.

nonpolar