Hydraulic conductivity of soil fully saturated with water is greater than the K value for the soil fully saturated with tetrachloroethylene (PCE)

To determine why the hydraulic conductivity of soil saturated with water is greater than the K value for the soil saturated with tetrachloroethylene (PCE), we need to understand what hydraulic conductivity and K value represent.

Hydraulic conductivity is a measure of a soil's ability to transmit water through it. It defines how easily water can flow through the soil, and it depends on various factors such as soil texture, porosity, and moisture content. The higher the hydraulic conductivity, the more easily water can move through the soil.

On the other hand, the K value for a substance like tetrachloroethylene (PCE) represents its permeability through the soil. Permeability is the ability of a substance to flow or pass through a porous medium, such as soil. The K value for PCE indicates how easily PCE can move through the soil.

Now, the reason why the hydraulic conductivity of soil saturated with water is usually greater than the K value for soil saturated with PCE is due to several factors:

1. Soil structure and pore size distribution: Water molecules are smaller than PCE molecules, so the larger pore spaces in the soil that allow water to pass through more easily might be smaller in size compared to the ones that would allow PCE to pass through.

2. Solubility and affinity: Water is a highly polar molecule and is often considered the universal solvent, meaning it can dissolve a wide range of substances. Therefore, water has a higher likelihood of dissolving and transporting impurities or contaminants present in the soil, including PCE. As a result, water can carry PCE along with it as it flows through the soil, contributing to its higher hydraulic conductivity.

3. Viscosity differences: Water has a lower viscosity compared to PCE. Viscosity is a measure of a fluid's resistance to flow. Lower viscosity allows water to flow more easily through the soil, increasing its hydraulic conductivity.

It's important to note that the actual hydraulic conductivity and K value of a specific soil can be influenced by various factors such as soil composition, compaction, and temperature. Therefore, varied soil characteristics might yield different results in specific scenarios.