Gasoline is a mixture of hydrocarbons of various chain lengths, ranging from 5-carbon chains to 10-carbon chains. One of the hydrocarbons we often hear about is the 8-carbon chain, octane. Octane combusts with oxygen as given by the balanced equation:

2C8H18(g) + 25O2(g) → 16CO2(g) + 18H2O(g)

Recall that you cannot infer the reaction pathway from the balanced equation. It must be derived experimentally. Yet upon reading this balanced equation, it appears unlikely that the combustion of octane occurs in a single step. Why?

One molecule of octane must react with 12.5 molecules of oxygen and that is unlikely to occur in one step.

Unimolecular equation are common, bimolecular reactions are fairly common and there are a few termolecular reactions that occur. But it is not likely that 1 molecule of octane and 12+ molecules of oxygen will bump into each other at the same exact instant to cause a reaction. Therefore, it must go through several steps.

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Upon reading the balanced equation for the combustion of octane, it appears unlikely that the reaction occurs in a single step because of the large number of molecules involved in the reaction. The equation shows that two molecules of octane (C8H18) react with 25 molecules of oxygen (O2) to produce 16 molecules of carbon dioxide (CO2) and 18 molecules of water (H2O).

Typically, chemical reactions occur through a series of intermediate steps. Complex reactions like the combustion of octane often involve multiple steps, with various intermediate species forming and then reacting further to produce the final products. In this case, it is improbable that the reaction occurs in a single step due to the large number of molecules involved and the complexity of the reaction.

To determine the actual reaction pathway of the combustion of octane, it is necessary to conduct experiments to observe and analyze the intermediate products and reaction rates. These experiments may involve techniques such as spectroscopy or mass spectrometry to identify the intermediate species and determine their concentrations over time. By studying the reaction kinetics and observing any intermediate steps, scientists can ultimately determine the true reaction pathway for the combustion of octane.