Are the intermolecular forces that are acting ont the molecule HF as follows: dipole-dipole, ionic and hydrogen bond

I think dipole-dipole and H bonding are inTERmolecular forces (between molecules) but I don't see how ionic forces get into the act. There is some ionic character to the H-F molecule from the intramolecular (within the same molecule) forces.

http://en.wikipedia.org/wiki/Intermolecular_force

Yes, the intermolecular forces acting on the molecule HF include dipole-dipole interactions, hydrogen bonding, and London dispersion forces.

To determine the intermolecular forces that act on a molecule, you need to consider the polarity of the molecule and the presence of hydrogen bonded to electronegative atoms.

Firstly, HF is a polar molecule due to the electronegativity difference between hydrogen and fluorine. The fluorine atom is more electronegative, causing a partial negative charge (δ-) around it, while the hydrogen atom acquires a partial positive charge (δ+). This uneven distribution of charges creates a dipole moment, resulting in dipole-dipole interactions. These forces are relatively strong compared to other intermolecular forces.

Secondly, HF can also participate in hydrogen bonding. Hydrogen bonding occurs when hydrogen atoms, bonded to an electronegative atom (such as oxygen, nitrogen, or fluorine), interact with lone pairs of electrons on other electronegative atoms nearby. In HF, the hydrogen atom is bonded to the highly electronegative fluorine atom, allowing it to form hydrogen bonds with other HF molecules or other molecules that have available lone pairs of electrons. Hydrogen bonds are stronger than typical dipole-dipole interactions due to their specific nature.

Lastly, London dispersion forces exist in all molecules to some extent. These forces are the result of temporary fluctuations in electron distribution, leading to transient dipoles. While London dispersion forces are generally weaker than dipole-dipole interactions and hydrogen bonding, they still contribute to the overall intermolecular forces acting on a molecule.

In summary, the intermolecular forces acting on the molecule HF include dipole-dipole interactions, hydrogen bonding, and London dispersion forces.