I am a main group element.

I have 3 p-orbital electrons in my valence shell.
I have a lower first ionization energy than arsenic.
I am not the largest atom in my group.
What element am I?

Antimony

Based on the given information, you can be Boron (B).

Here's why:
1. Boron (B) is a main group element, specifically belonging to Group 13 (or Group IIIA) on the periodic table.
2. Boron has 3 valence electrons, which are located in the p-orbital. This means it has 3 p-orbital electrons in its valence shell.
3. Boron has a lower first ionization energy than arsenic (As). Ionization energy is the energy required to remove an electron from an atom. Generally, Boron has a lower ionization energy than arsenic.
4. Although Boron is not the largest atom in its group, it is smaller than its neighboring elements Aluminum (Al) and Gallium (Ga), which have more electrons and occupy a higher position in Group 13.

Therefore, based on the given criteria, the element you are is Boron (B).

To determine the element described, we need to identify a main group element (also known as a representative element) with the given characteristics.

First, let's consider the statement "I have 3 p-orbital electrons in my valence shell." This indicates that the element is from Group 13 of the periodic table, as elements in this group have three valence electrons in their outermost shell.

Next, we have the clue "I have a lower first ionization energy than arsenic." The ionization energy refers to the energy required to remove an electron from an atom, and elements with lower ionization energies generally have a weaker hold on their outermost electrons. Comparing to arsenic (As), which has a relatively high ionization energy, we are looking for an element with a lower value.

Lastly, we have the statement "I am not the largest atom in my group." This implies that the element is not the largest atom in Group 13, which means it is not at the bottom of the group.

Putting these clues together, we can determine that the element being described is Boron (B). Boron is in Group 13, has 3 p-orbital electrons, has a lower first ionization energy than arsenic, and is not the largest atom in the group.

Therefore, the element in question is Boron (B).