I am a five digit number. Digit at ones place is same as digit at tens place and their sum is 2. Digit at ten thousands place is the largest one digit even number. Face value of the digit at hundreds place is 3. Difference of digit at ten thousands place and digit at hundred place will give you digit at thousands place.

85,311

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To find the five-digit number, let's go step by step:

1. "Digit at ones place is the same as digit at tens place, and their sum is 2."
This means the ones and tens place digits must be two digits that add up to 2. The only two single-digit numbers that add up to 2 are 1 and 1. Therefore, the ones and tens place digits are both 1.

2. "Digit at ten thousands place is the largest one-digit even number."
The largest one-digit even number is 8, so the ten thousands place digit is 8.

3. "The face value of the digit at the hundreds place is 3."
The face value refers to the actual value of the digit. Therefore, the hundreds place digit is 3.

4. "The difference of the digit at the ten thousands place and the digit at the hundred place will give you the digit at the thousands place."
The difference between 8 (ten thousands place) and 3 (hundreds place) is 5. Therefore, the thousands place digit is 5.

Putting all the digits together, we have:
Digit at ten thousands place: 8
Digit at thousands place: 5
Digit at hundreds place: 3
Digit at tens place: 1
Digit at ones place: 1

So, the five-digit number is 85,311.