the ground stste energy of H- atom is -13.6 eV. the energy needed to ionise H- atom from its second excited state is

1.51 eV
3.4 eV
13.6 eV
12.1 eV

To find the energy needed to ionize the H- atom from its second excited state, we need to know the energy levels of the H- atom. The energy levels of the hydrogen atom can be calculated using the Rydberg formula:

E_n = -13.6 eV / n^2

Where E_n is the energy of the hydrogen atom at the nth energy level, and n is the principal quantum number.

In the case of the H- atom, the ground state energy is given to be -13.6 eV. This corresponds to n = 1.

For the second excited state, we need to find the value of n. To determine this, we can use the fact that the energy levels are given by n = 1, 2, 3, ...

Thus, the second excited state corresponds to n = 3.

Plugging in n = 3 into the Rydberg formula, we get:

E_3 = -13.6 eV / (3^2) = -13.6 eV / 9 ≈ -1.51 eV

Therefore, the energy needed to ionize the H- atom from its second excited state is approximately 1.51 eV.

Therefore, the correct answer is 1.51 eV.

That state is 13.6 eV/(2^2) = 3.4 eV below the ionization limit, since the principal quantum number is 2.