If one gram of aspirin is dissolved in 100mL of water at 37 degrees celsius, how much aspirin will precipitate out of solution when it is cooled to 25 degrees celsius?
To determine the amount of aspirin that will precipitate out of the solution as it cools from 37 degrees Celsius to 25 degrees Celsius, we need to calculate the solubility of aspirin at both temperatures.
1. Find the solubility of aspirin at 37 degrees Celsius:
The solubility of aspirin in water at 37 degrees Celsius is approximately 3.0 g/100 mL.
2. Find the solubility of aspirin at 25 degrees Celsius:
The solubility of aspirin in water at 25 degrees Celsius is approximately 1.1 g/100 mL.
3. Calculate the difference in solubility between the two temperatures:
Difference = Solubility at 37 degrees Celsius - Solubility at 25 degrees Celsius
= 3.0 g/100 mL - 1.1 g/100 mL
= 1.9 g/100 mL
4. Calculate the amount of aspirin that will precipitate out:
The initial solution contains 1 gram of aspirin in 100 mL of water.
Since the difference in solubility is 1.9 g/100 mL, for every 100 mL of the solution, 1.9 grams of aspirin will precipitate out as the temperature is lowered.
To determine the amount for the given 100 mL of solution, we calculate:
Amount of aspirin precipitated = (1.9 g/100 mL) * (100 mL / 100 mL) = 1.9 grams
Therefore, when the solution is cooled from 37 degrees Celsius to 25 degrees Celsius, 1.9 grams of aspirin will precipitate out of the solution.
To calculate the amount of aspirin that will precipitate out of solution when cooled from 37°C to 25°C, we need to determine the solubility of aspirin at the corresponding temperatures. The solubility of a substance is typically given in terms of grams of solute per 100 mL of solvent.
Here's the general approach to solve this problem:
1. Find the solubility of aspirin at 37°C and 25°C.
2. Calculate the amount of aspirin initially dissolved in 100 mL of water (at 37°C).
3. Determine the change in solubility as the solution is cooled.
4. Calculate the amount of aspirin that will precipitate out of solution when cooled to 25°C.
Let's break down each step:
1. Find the solubility of aspirin at 37°C and 25°C:
Solubility of aspirin is typically given in grams of aspirin per 100 mL of water. You can refer to a solubility chart or consult reliable sources to find the solubility values for aspirin at specific temperatures. For example, assume the solubility of aspirin at 37°C is 3 grams per 100 mL and at 25°C is 2 grams per 100 mL.
2. Calculate the amount of aspirin initially dissolved in 100 mL of water (at 37°C):
We are given 1 gram of aspirin initially dissolved in 100 mL of water at 37°C. So, the concentration of aspirin in the solution is 1 gram per 100 mL.
3. Determine the change in solubility as the solution is cooled:
The change in solubility can be obtained by subtracting the solubility at the lower temperature from the solubility at the higher temperature. In this case, the change in solubility is 3 grams per 100 mL (solubility at 37°C) - 2 grams per 100 mL (solubility at 25°C) = 1 gram per 100 mL.
4. Calculate the amount of aspirin that will precipitate out of solution when cooled to 25°C:
As we have 100 mL of solution, and for every 100 mL, there is 1 gram less solubility, the amount of aspirin that will precipitate out of solution when cooled is 1 gram.
Therefore, when the solution is cooled from 37°C to 25°C, 1 gram of aspirin will precipitate out of the solution.