How many moles of ozone does the atmosphere hold? For a sense of scale,compare the amount to the total carbon dioxide emitted annually from fossil fuel burning, cement production and deforestation (7900 Tg/C). Given with the facts the amount of ozone is equivalent to a 3mm band around earth, standard temperature and pressure is at 22.4dm^3 with the radius of earth 6378km.

To find the number of moles of ozone in the atmosphere, we can use the given information about the thickness of the ozone layer and the radius of the Earth.

We are given that the thickness of the ozone layer is equivalent to a 3mm band around the Earth. Let's convert this thickness to meters.

Thickness of ozone layer = 3mm = 3 × 10^(-3) m

The volume occupied by the ozone layer can be calculated using the formula for the volume of a cylinder:

Volume = π * r^2 * h

We are interested in the volume of the ozone layer surrounding the Earth, so the radius (r) can be obtained by adding the Earth's radius to the thickness of the ozone layer:

r = 6378 km + 3 mm
= 6378 km + 3 × 10^(-3) km
= 6378 km + 3 × 10^(-6) km
= 6378 km + 3 × 10^(-6) × 1000 km (since 1 km = 1000 m)
= 6378 km + 0.003 km
= 6378.003 km

Now we need to convert the radius to meters:

r = 6378.003 km × 1000 m/km
= 6378003 m

The volume can be calculated as:

Volume = π * (6378003 m)^2 * (3 × 10^(-3) m)

Now we know the volume of the ozone layer, but we need to calculate the number of moles of ozone. To do this, we can use the ideal gas law:

PV = nRT

Where:
P = pressure (standard pressure = 1 atm = 1.013 × 10^5 Pa)
V = volume (in liters)
n = number of moles
R = ideal gas constant (0.0821 L·atm/(mol·K))
T = temperature (standard temperature = 273 K)

Rearranging the equation, we get:

n = PV / RT

Since we have the volume of the ozone layer (in cubic meters), we need to convert it to liters:

Volume (in liters) = Volume (in cubic meters) / 1000

Now we can calculate the number of moles of ozone:

n = (1 atm) * (Volume (in liters)) / (0.0821 L·atm/(mol·K)) * (273 K)

Substitute the values we have:

n = (1 atm) * (Volume (in cubic meters) / 1000 L) / (0.0821 L·atm/(mol·K)) * (273 K)

Now we can put all the values we have into the equation and calculate the number of moles of ozone in the atmosphere.

Please note that the actual calculation may require a scientific calculator or a computer program to obtain an accurate result.