Why are the molecules of hydrocarbons nonpolar?

The intermolecular attractions are strong.
The electron pair is shared almost equally in all the bonds.
All the bonds are single covalent bonds***
Van der Waals forces overcome polarity

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The reason why the molecules of hydrocarbons are nonpolar is primarily due to the nature of their chemical bonds. Hydrocarbons consist mainly of carbon and hydrogen atoms bonded together. The carbon-hydrogen bonds in hydrocarbons are generally nonpolar covalent bonds.

A covalent bond is formed when two atoms share electrons. In a nonpolar covalent bond, the shared electron pair is distributed equally between the two atoms. In the case of hydrocarbons, such as methane (CH4) or ethane (C2H6), all the carbon-hydrogen bonds are single covalent bonds. These single covalent bonds are formed by the sharing of two electrons, one from the carbon atom and one from the hydrogen atom.

Since the electronegativity (the ability to attract electrons) of carbon and hydrogen atoms is similar, the shared electron pair is distributed almost equally between the carbon and hydrogen atoms. This equal sharing of electrons creates a symmetrical distribution of charge within the hydrocarbon molecule. As a result, there are no significant differences in electronegativity to create regions of partial positive or partial negative charge in the molecule. Hence, hydrocarbons are nonpolar molecules.

It's important to note that although hydrocarbons are nonpolar at the molecular level, they can still experience intermolecular attractions known as van der Waals forces. Van der Waals forces are relatively weak compared to ionic or covalent bonds but play a role in interactions between hydrocarbon molecules. However, these forces do not overcome the overall nonpolarity of the hydrocarbon molecules themselves.