Are hydrocarbons always nonpolar??

Yes

Most hydrocarbons are non-polar but don't forget that acetylene (or other alkynes in which the triple bond and H are on the end) is acidic.

Hydrocarbons can be both polar and nonpolar, depending on their molecular structure. Hydrocarbons consist of only carbon and hydrogen atoms bonded together.

If the hydrocarbon molecule contains only carbon-carbon (C-C) and carbon-hydrogen (C-H) bonds and has a symmetrical shape, it will be nonpolar. Nonpolar molecules have an equal distribution of charge across the molecule, meaning that the electron density is balanced.

However, if the hydrocarbon has other atoms, such as oxygen (O), nitrogen (N), or halogens (e.g., chlorine, bromine), and/or contains functional groups like alcohols, amines, or carboxylic acids, it can become polar. Polar molecules have an uneven distribution of charge across the molecule, meaning that there is a separation of positive and negative charges.

To determine if a specific hydrocarbon is polar or nonpolar, you can follow these steps:

1. Identify the atoms and functional groups present in the molecule.
2. Determine the polarity of each bond based on the electronegativity difference between the atoms involved. Electronegativity is a measure of the atom's ability to attract electrons towards itself.
3. Consider the overall molecular shape. Symmetrical molecules tend to be nonpolar, while asymmetrical or polar functional groups can contribute to the molecule's polarity.
4. Assess the individual bond polarities and molecular shape to determine if the molecule has an overall dipole moment (uneven distribution of charge) or not.

Remember that even if a hydrocarbon molecule contains polar functional groups, it may still be mostly nonpolar if its overall shape and arrangement of atoms cancel out the polarity, resulting in a nonpolar molecule.

It's always a good idea to use molecular modeling software or refer to physical chemistry references to help visualize and determine the polarity of specific hydrocarbon molecules.