Calculate the value of the [Fe3+]/[Fe2+] if 3 cm3 of the 0.05 M Fe3+ solution is added to 25 cm3 of the 0.05 M Fe2+ solution

To calculate the value of [Fe3+]/[Fe2+], we need to determine the moles of Fe3+ and Fe2+ in each solution.

Given:
Volume of Fe3+ solution (V1) = 3 cm^3
Molarity of Fe3+ solution (M1) = 0.05 M

The moles of Fe3+ can be calculated using the formula:
moles = Molarity * Volume (in liters)

Moles of Fe3+ (n1) = M1 * V1 / 1000 (converting cm^3 to liters)
= 0.05 * 3 / 1000
= 0.00015 mol

Now, let's look at the Fe2+ solution.

Volume of Fe2+ solution (V2) = 25 cm^3
Molarity of Fe2+ solution (M2) = 0.05 M

Moles of Fe2+ (n2) = M2 * V2 / 1000 (converting cm^3 to liters)
= 0.05 * 25 / 1000
= 0.00125 mol

Finally, we can calculate [Fe3+]/[Fe2+] by dividing the moles of Fe3+ by the moles of Fe2+:

[Fe3+]/[Fe2+] = n1 / n2
= 0.00015 / 0.00125
= 0.12

Therefore, the value of [Fe3+]/[Fe2+] is 0.12.

To calculate the value of [Fe3+]/[Fe2+], we need to determine the number of moles of Fe3+ and Fe2+ in each solution.

First, let's calculate the number of moles of Fe3+ in the 3 cm³ of the 0.05 M Fe3+ solution:

Number of moles of Fe3+ = concentration (M) × volume (L)
= 0.05 mol/L × 0.003 L
= 0.00015 mol

Next, let's calculate the number of moles of Fe2+ in the 25 cm³ of the 0.05 M Fe2+ solution:

Number of moles of Fe2+ = concentration (M) × volume (L)
= 0.05 mol/L × 0.025 L
= 0.00125 mol

Now, we can determine the ratio of [Fe3+]/[Fe2+]:

[Fe3+]/[Fe2+] = (moles of Fe3+) / (moles of Fe2+)
= 0.00015 mol / 0.00125 mol
= 0.12

Therefore, the value of [Fe3+]/[Fe2+] is 0.12.

Is this before or after the disproportionation.

Before:
(Fe^3+) =- 0.05 x 3/28 = ?
(Fe^2+) = 0.05 x 25/28 = ?
or more simply, it is
[(0.05 x 3/25)/(0.05 x 25/28)] or just 3/25 = ?