What is cation exchange? How is the best way to plot surface water or groundwater data to see if you have cation exchange?

Can you recommend references to learn more about this?
Thank you

Have you tried Googling?

Cation exchange is the process of a mixture flowing through a system in which the cations ( K, Ca, Mg, Fe, Mn, etc) are exchanged for another positive ion, usually H^+. Sometimes it goes through two steps, the first changing to Na^+ and the second exchanging all the Na for H. I would think milliequivalents/L something like that would provide the data you need.

After thinking about this for a short time, I assume the context in which you are using cation exchange, is that any one or more cations can exchange for another more abundant cation in ground water.

DrBOB222 -

So, if I have cation data for Surface water and groundwater...how do I plot the data to see if I have cation exchange going on.
Would I just begin plotting any given cation on the x-axis and another cation on the y-axis and then what...what would the graph look like if there was exchange happening.
I guess I am trying to find out if these waters (surface water and shallow groundwater) are coming into contact at all (i.e., mixing).

Cation exchange refers to a process that occurs in soils or other solid materials where positively charged ions (cations) are exchanged between the material and the surrounding water. This process is important in understanding how nutrients, contaminants, and other elements are transported and retained in soil and water systems.

To plot surface water or groundwater data to determine if cation exchange is happening, you can follow these steps:

1. Collect Data: Gather relevant data on the concentrations of cations (e.g., calcium, magnesium, potassium, sodium) in both the water and the solid material involved (such as soil or aquifer sediment).

2. Identify Patterns: Plot your data on a graph, with the x-axis representing the concentration of cations in the solid material, and the y-axis representing the concentration of cations in the water. Look for any patterns or trends that emerge.

3. Analyze the Relationship: Analyze the plotted data to determine if there is a linear or non-linear relationship between the cation concentrations in the solid material and the water. This relationship can provide insights into the occurrence and extent of cation exchange.

4. Interpret the Results: If a clear relationship exists between the concentrations of cations in the solid material and the water, it suggests that cation exchange is likely occurring. The strength and nature of the relationship can provide additional information about the magnitude and efficiency of the cation exchange process.

To learn more about cation exchange and related topics, here are some recommended references:

1. "Soil Chemistry" by Daniel G. Strawn and Hinrich L. Bohn
- This comprehensive textbook covers various aspects of soil chemistry, including cation exchange processes.

2. "Environmental Soil Chemistry" by Donald L. Sparks
- This book provides an in-depth exploration of soil chemistry concepts, including cation exchange and its role in environmental systems.

3. "Fundamentals of Soil Physics" by Daniel Hillel
- This book offers a thorough introduction to soil physics, including topics on soil-water interactions and ion transport mechanisms.

4. "Environmental Hydrology" by Andy D. Ward and Stanley W. Trimble
- This textbook explores hydrological processes, including the interaction between water and solid materials, such as soils and aquifers.

Remember to utilize academic journals, scientific databases, and online resources for additional research on cation exchange, as these sources often provide up-to-date information and research findings.