why the surface tension of water is greater tha that of methylated spirit?

The surface tension of a liquid refers to the force that acts on the surface molecules, which causes the liquid to minimize its surface area and form droplets or maintain a specific shape. The surface tension of water is higher compared to that of methylated spirit due to the properties of their respective molecules.

To understand why the surface tension of water is greater than that of methylated spirit, we need to consider the molecular properties of both substances. Water (H2O) and methylated spirit (which usually contains ethanol, CH3CH2OH) have different molecular structures and intermolecular forces.

Water molecules are polar, meaning they have a positively charged hydrogen end and a negatively charged oxygen end. These polar molecules can form hydrogen bonds with neighboring water molecules, creating a network of interconnected forces. These hydrogen bonds provide strong attractions between water molecules, leading to a high surface tension.

On the other hand, methylated spirit contains ethanol, which has a different molecular structure. Ethanol molecules are also polar but have a shorter chain length compared to water. Although ethanol molecules can form hydrogen bonds, they are not as extensive or strong as the hydrogen bonds formed in water.

The weaker intermolecular forces in methylated spirit result in lower surface tension compared to water. Additionally, the presence of other compounds in methylated spirit, such as denaturants or additives, may further contribute to the lower surface tension.

In summary, the difference in molecular structure and intermolecular forces between water and methylated spirit leads to a higher surface tension in water. Water's polar nature and extensive hydrogen bonding provide stronger attractions between its molecules, resulting in a greater resistance to surface area expansion.