Oil and water don't mix. We say that oil is

a heterogenous mixture

Oil is non-polar.

Oil is hydrophobic, meaning it repels or does not mix with water. This occurs because oil molecules consist of long chains of carbon atoms bonded to hydrogen atoms, making them nonpolar. On the other hand, water molecules are highly polar, with oxygen atoms having a slightly negative charge and hydrogen having a slightly positive charge.

To understand why oil and water don't mix, we need to consider the concept of intermolecular forces. In water, there are strong hydrogen bonds between water molecules. These bonds arise due to the attraction between the slightly negative oxygen atom of one water molecule and the slightly positive hydrogen atom of another water molecule.

On the other hand, oil lacks such strong intermolecular forces. Instead, the long nonpolar carbon chains in the oil molecules experience weak Van der Waals forces between one another. These forces are relatively weaker than hydrogen bonds. Due to the differences in intermolecular forces, oil does not dissolve in water and forms distinct layers when mixed.

If you have oil and water mixed together and want to separate them, you can use the following steps:

1. Let the oil-water mixture sit undisturbed for some time to allow the two substances to separate on their own. This is because oil and water have different densities, with oil being less dense and floating on top.

2. Use a separatory funnel or a similar device to carefully pour off the oil layer from the top, while leaving behind the water layer at the bottom. This separation is possible because oil and water do not mix.

It's important to note that even though oil and water don't mix, they can be temporarily combined using additives called emulsifiers. These substances help stabilize mixtures called emulsions, such as mayonnaise or salad dressings, by preventing the separation of oil and water. In these cases, the emulsifier molecules have properties that allow them to interact with both water and oil, creating stable mixtures.