In state-of-the-art vacuum systems, pressures as low as 1.00 10-9 Pa are being attained. Calculate the number of molecules in a 1.80-m3 vessel at this pressure and a temperature of 31.0°C.

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To calculate the number of molecules in a vessel at a given pressure and temperature, we can use the ideal gas law equation:

PV = nRT

Where:
P = pressure (in Pascals)
V = volume (in cubic meters)
n = number of moles of gas
R = ideal gas constant (8.314 J/(mol·K))
T = temperature (in Kelvin)

First, we need to convert the pressure from 1.00 × 10^(-9) Pa to the same unit as the ideal gas constant. The ideal gas constant is usually expressed in units of J/(mol·K), so we need to convert Pascals to atmospheric pressure. 1 atmosphere (atm) is roughly equal to 101325 Pascals.

1 atm = 101325 Pa

Therefore, the pressure in atm is:

P = (1.00 × 10^(-9) Pa) / (101325 Pa/atm) ≈ 9.87 × 10^(-15) atm

Next, let's convert the temperature from 31.0°C to Kelvin:

T = 31.0°C + 273.15 ≈ 304.15 K

Now we can rearrange the ideal gas law to solve for the number of moles (n):

n = PV / RT

n = (9.87 × 10^(-15) atm) * (1.80 m^3) / ((8.314 J/(mol·K)) * (304.15 K))

Simplifying the equation gives:

n ≈ 6.0 × 10^(-15) mol

Finally, we know that there are approximately 6.022 × 10^23 molecules in one mole of any substance (Avogadro's number), so we can find the number of molecules by multiplying the number of moles by Avogadro's number:

Number of molecules = (6.0 × 10^(-15) mol) * (6.022 × 10^23 molecules/mol)

Number of molecules ≈ 3.61 × 10^9 molecules

Therefore, at a pressure of 1.00 × 10^(-9) Pa and a temperature of 31.0°C, there are approximately 3.61 × 10^9 molecules in a 1.80-m^3 vessel.