which pairing below does not correctly match the scientist with the contribution to the understanding of the atom

A. Proust and the realization that the elements of compounds are found in certain proportions by mass
B. Thomson and the law of definite proportions.
C. Dalton and the initial proposal of the atomic theory of matter
D. Rutherford and the understanding that the atom has a small, dense nucleus with a positive charge

I think I would look at B is the incorrect one.

To determine which pairing does not correctly match the scientist with the contribution to the understanding of the atom, let's analyze each option:

A. Proust and the realization that the elements of compounds are found in certain proportions by mass.
Joseph Louis Proust did contribute to the understanding of chemistry, specifically regarding the law of definite proportions. This law states that a given compound always contains its constituent elements in fixed and definite proportions by mass. This pairing seems to be accurate.

B. Thomson and the law of definite proportions.
J.J. Thomson, on the other hand, is known for his work on cathode ray experiments and the discovery of the electron. He proposed the "plum pudding" model of the atom, which implicated a positively charged substance with negatively charged electrons scattered throughout it. Therefore, the pairing of Thomson with the law of definite proportions is incorrect.

C. Dalton and the initial proposal of the atomic theory of matter.
John Dalton is often referred to as the father of modern atomic theory. He was the first to introduce the concept that atoms are tiny, indivisible particles that combine to form compounds. This pairing is correct.

D. Rutherford and the understanding that the atom has a small, dense nucleus with a positive charge.
Ernest Rutherford conducted the gold foil experiment, which led him to propose that atoms have a small, dense nucleus at their center, surrounded by electrons. This pairing is also correct.

Therefore, the correct answer to the question is:

B. Thomson and the law of definite proportions.