2 trains leave the station at 325 one going east at 66 miles per hour the second going west at 82 miles per hour they are 111 miles apart what time is it

The pull apart at 66+82 = 150 mi/hr.

So, it only takes 111/150 = 0.74 hours to get 111 miles apart.

That is 44'24", so it will happen at 3:25:00 + 0:44:24 = 4:09:24

You sure do make it hard to parse your text, what with no punctuation and garbled syntax!