4KCl + 4HNO3 + O2 ==> 4KNO3 + 2Cl2 + 2H2O

what kind of reaction is this?

redox

The reaction you mentioned is a chemical reaction known as a redox (reduction-oxidation) reaction. It involves both oxidation and reduction reactions that occur simultaneously.

In this reaction, the potassium chloride (4KCl) and nitric acid (4HNO3) react with the presence of oxygen (O2) to form potassium nitrate (4KNO3), chlorine gas (2Cl2), and water (2H2O).

To determine the type of reaction, we can break it down into the oxidation and reduction half-reactions:

Oxidation half-reaction:
2Cl⁻(aq) ⟶ Cl₂(g) + 2e⁻

Reduction half-reaction:
4H⁺(aq) + 4e⁻ ⟶ 2H₂O(l)

From these half-reactions, we can see that chlorine gas (Cl₂) is formed by the oxidation of chloride ions (Cl⁻) and water (H₂O) is formed by the reduction of hydronium ions (H⁺). This indicates that chlorine is being reduced (gaining electrons) and hydronium ions are being oxidized (losing electrons).

Therefore, the overall reaction is a redox reaction because there is both oxidation and reduction occurring.