How do I separate a mixture of liquids?

If they are homogenous (miscible), you can use distillation or try to freeze one of them out. Neither technique is perfect; the removed material is not 100% pure. Repeated applications may be necessary

If they are not miscible and form two phases then these can be physically separated using a separating funnel.

http://en.wikipedia.org/wiki/Separating_funnel

There are other methods if there are very small amounts of the liquids.

To separate a mixture of liquids, you can use one or more of the following techniques:

1. Distillation: This method is used to separate liquids with different boiling points. The mixture is heated, and the liquid with the lower boiling point evaporates first. The vapor is then condensed and collected, leaving behind the liquid with the higher boiling point.

2. Fractional distillation: Similar to distillation, but used when there is a small difference in boiling points between the liquids in the mixture. Fractionating columns are used to provide more surface area for vaporization and condensation, resulting in better separation.

3. Simple gravity separation: If the liquids in the mixture have different densities, the lighter liquid can be separated by pouring off or siphoning it from the top, while the heavier liquid remains at the bottom.

4. Separatory funnel: This technique utilizes the difference in density between the liquids. The mixture is poured into a separatory funnel, allowed to settle, and then the lower liquid can be drained off while the upper liquid is retained.

5. Solvent extraction: If the liquids are not miscible (do not mix), a solvent can be added which selectively dissolves one of the liquids, allowing it to be separated from the other. The solvent is then evaporated to recover the separated liquid.

It is important to note that the specific separation technique to use depends on the properties of the liquids in the mixture and their desired separation. Always refer to safety guidelines and proper equipment when performing any separation process.