# College Chemistry

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1. What is the change in internal energy (in J) of a system that absorbs 0.677 kJ of heat from its surroundings and has 0.438 kcal of work done on it?

2. A 30.5 g sample of an alloy at 94.0°C is placed into 48.7 g water at 20.3°C in an insulated coffee cup. The heat capacity of the coffee cup (without the water) is 9.2 J/K. If the final temperature of the system is 31.1°C, what is the specific heat capacity of the alloy? (c of water is 4.184 J/g×K)

3. When 33.5 mL of 0.535 M H2SO4 is added to 33.5 mL of 1.07 M KOH in a coffee-cup calorimeter at 23.50°C, the temperature rises to 30.17°C. Calculate H of this reaction per mole of H2SO4 and KOH reacted. (Assume that the total volume is the sum of the individual volumes and that the density and specific heat capacity of the solution are the same as for pure water: d = 1.00 g/mL and c = 4.184 J/g×K.)

4. Organic hydrogenation reactions, in which H2 and an "unsaturated" organic compound combine, are used in the food, fuel, and polymer industries. In the simplest case, ethene (C2H4) and H2 form ethane (C2H6). If 124 kJ is given off per mole of C2H4 reacting, how much heat is released when 14.6 kg of C2H6 forms?

Can someone please explain how to do these problems ?

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