chemistry lab
posted by anonymous .
1) What does a high Boltzmann Distribution value indicate? (please explain I already read wikepedia articles)
2) For fluoroacetic acid the highest Boltzmann Distribution is when the dihedral angle is at 0°.
However, going from chloro to bromo and then to iodoacetic acid, there is an increasing dip
in the Boltzmann Distribution. What is responsible for this “dip”?
3) Ignoring the “dip” mentioned in #2, what is the “general” relationship between dipole and
Boltzmann Distribution for the haloacetic acids?
a. ANTI conformers have a (low/high) dipole and a (low/high) Boltzmann Distribution.
b. The SYN conformers have a (low/high) dipole and a (low/high) Boltzmann Distribution.
4) For haloacetic acids, which is more acidic: a conformer with a high dipole or a low
dipole? (Circle one.)
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