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Chemistry

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Determine the potential (in V) of an electrochemical cell using a gold electrode and gold (III) [0.0243 M] solution in combination with a manganese/manganese (II) [0.00567 M] half cell


How on earth would I do this question?

I just know

Au(3+) + 3e- = Au and E = 1.22 V

  • Chemistry -

    The half reactions are:
    Mn^2+(aq) + 2e- --> Mn(s) Eo = -1.18
    Au^3+(aq) + 3e- --> Au(s) Eo = 1.50***
    (***NOTE: That is the value I was able to find)
    Since Mn oxidizes more easily than Au, the Mn/Mn^2+ half reaction occurs as an oxidation:
    Mn(s) --> Mn^2+(aq) + 2e- Eo = +1.18
    The overall reaction is:
    2Au^3+(aq) + 3Mn(s) --> 2Au(s) + 3Mn^2+(aq)
    Keq = [Mn+2]^3/[Au+3]^2
    The Eo (standard potential for the entire electrochemical cell is 1.50 + 1.18 = 2.68 volts
    Eo(overall) = 2.68v
    The standard cell potential assumes standard conditions: 1M solutions and 1 atm pressure for gasses present.
    Since you DO NOT HAVE 1M solutions, you must use the Nernst Equation:
    E(cell) = Eo - [0.0592/n][log(Q)]
    Q = [Mn+2]^3 / [Al+3]^2
    (Same as the Keq BUT the concentrations are the initial ones rather than the equilibrium ones)
    E(cell) = 2.68 - [0.0592/6][log[(0.00567)^3/(0.0243^2)] = _______?

  • Chemistry -

    Awesome Thanks So Much.

    But.. how do you know that in the Nernst Equation n = 6

    Besides that it makes sense.. thanks again!

  • Chemistry -

    The Mn rxn is 2e, the Au rxn is 3e.
    Multiply Mn rxn by 3 and Au rxn by 2 and add the two equations together. That gives 6 electrons; therefore, n is 6 in the reaction.

  • Chemistry -

    The two half reaction must be reconciled on the number of electrons by multiplying the first one by 3 and the second one by 2:
    3Mn(s) --> 3Mn^2+(aq) + 6e-
    2Au^3+(aq) + 6e- --> 2Au(s)
    ----------------------------
    3Mn(s) + 2Au^3+(aq) + 6e- --> 3Mn^2+(aq) + 2Au(s) + 6e-
    The 6e-'s on each side are usually cancelled out in the overall reaction but they can't be forgotten.

  • Chemistry -

    Oh Okay!

    Wow you guys are awesome. Thanks!!

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