a chemical test to distinguish between a sample of iron and a sample of iron sulphide.

Which iron sulfide are you talking about? There are several. FeS2 looks like gold, and would not be mistaken for iron. An easy test would be to see if a magnet attracts the material, or if electricity can be conducted through it. If it does, it it metallic iron.

You can add hydrochloic acid and notice if the smell of H2S is detected.

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To distinguish between a sample of iron and a sample of iron sulfide, you can perform a simple chemical test using hydrochloric acid (HCl) and a magnet.

Here are the steps to conduct the test:

1. Obtain small pieces of both samples - the iron and iron sulfide.

2. Use a magnet to test the magnetic properties. Iron is a ferromagnetic material, which means it is strongly attracted to magnets. As a result, if the sample is pure iron, it will be attracted to the magnet. On the other hand, iron sulfide is not magnetically attracted.

3. Next, you can perform a reaction with hydrochloric acid (HCl). Take a small amount of HCl in a test tube and add a small piece of the sample.

4. If the sample is iron, it will react with HCl, producing hydrogen gas (H2) and iron chloride (FeCl2). The reaction can be represented as follows:
Fe + 2HCl → FeCl2 + H2

You will observe the formation of bubbles as the hydrogen gas is released. You may also notice that the iron sample dissolves or gradually breaks down.

5. On the other hand, iron sulfide will not react with HCl. Iron sulfide is resistant to acid and will remain mostly unchanged.

By conducting these two tests, you can determine whether your sample is iron or iron sulfide. Remember to exercise caution when using chemicals, and it's always best to perform experiments in a well-ventilated area and wear appropriate safety equipment, such as goggles and gloves.