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December 8, 2016

Search: Calculate the molarity (M) of a solution of the strong base KOH if the pH is 12.5.

Number of results: 50,504

Science
Calculate the molarity of 10 % HNO3 (w/w) solution if its density is 2.0 g/cc at 25° C.
October 2, 2016 by satyam kar

Chemistry
4 Questions on molarity that I really don't understand. I have the formulas, but they don't seem to fit in to the question right. Please take a look, thanks! 1. Calculate the weight, in grams, of HNO3 present in 1.0 litre of 0.10M of solution. 2. What is the concentration, in ...
October 25, 2015 by Bethany

Chemistry
I don't understand how to work out the volumes of weak acid and strong base to mix to make 1L of buffer when given the concentrations of weak acid and strong base (in my case 0.160M NaOH and 0.200M H3PO4) and the pH required (7.00). Specifically the textbook is Fundamentals of...
March 30, 2008 by Sarah

Chemistry
I don't understand how to work out the volumes of weak acid and strong base to mix to make 1L of buffer when given the concentrations of weak acid and strong base (in my case 0.160M NaOH and 0.200M H3PO4) and the pH required (7.00). Specifically the textbook is Fundamentals of...
March 30, 2008 by Sarah

chemistry please help!!
what is the net ionic equation for the reaction between a strong acid and a strong base? what does it mean by this question?/ (: thanks.
March 4, 2013 by yvette

Chemistry
Urgent... Someone please help!! Can someone please check to see if I am doing these correctly, I have a test tomorrow... Thank you :) Q) Calculate the new molarity of a 35mL sample of 0.450 M CaCl2 solution that is diluted with enough water to make 250 mL of solution. A) 0.450...
April 2, 2013 by Kishwa

Chemistry
Calculate the pH of a 5.90 10-3 M solution of H2SO4 I have tried doing this as pH=-log[H+] and also by multiplying the Molarity by two because there are two hydrogens and then doing the -log but both ways have gotten me the wrong answer is there something i am missing? same ...
March 5, 2012 by Ashley

Chemistry
What are the general equations for reaction of 1. Strong acid and weak base 2. Strong base and weak acid?
April 8, 2012 by chamy

Chemistry
Calculate the pH of the titration of 100.00 mL of 0.200 M HOCI with 0.400 M KOH after 0, 25.00, 50.00, & 75.00 mL of KOH have been added. The Ka for HOCI is .000000035...Please Help!!!!
April 17, 2010 by Need Chem Help

chemistry
calculate the PH during the titration of 50.00 ml of 0.300 M HNO3 with 0.600 M KOH after 0, 15.50, 25.00, and 40.00 ml of KOH have been added. Graph the titration curve
December 2, 2011 by saud

chemistry
calculate the PH during the titration of 50.00 ml of 0.300 M HNO3 with 0.600 M KOH after 0, 15.50, 25.00, and 40.00 ml of KOH have been added. Graph the titration curve. Ph=
December 2, 2011 by saud

Chemistry
Calculate the amount in moles and the mass in grams of KOH needed to convert 1.50 g of aluminum to KAl(OH)4. Balanced equation = 2 Al (s) + 2 KOH (aq) + 6 H2O (l) ¨ 2 KAl(OH)4 (aq) + 3 H2 (g)
February 29, 2012 by Cynthia

Chemistry
Calculate the amount in moles and the mass in grams of KOH needed to convert 1.50 g of aluminum to KAl(OH)4. Balanced equation = 2 Al (s) + 2 KOH (aq) + 6 H2O (l)->2 KAl(OH)4 (aq) + 3 H2 (g)
February 29, 2012 by Cynthia

chem
I posted a question earlier that I was having trouble with, but I was unable to attempt to try it again for several days after posting. The question was: A buffer is made up of .300 L each of .500 M KH2PO4 and .317 M K2HPO4. Assuming tha the volumes are additive, calculate a) ...
May 5, 2007 by James

chemistry2
Hydrochloric acid is sold as a concentrated acqueous solution. If the molarity of HCl is 12.0 and its density is 1.18 g/ml. calculate A) MOLALITY B)THE % BY MASS OF HCl in the solution
May 11, 2011 by Daniel Forero

Chem
A tank car containing concentrated HCL (molarity 12.1) derails and spills exactly 1500 L of acid. Solid potassium hydroxide is required ot neutralize the spill. (a) Write a balanced chemical equation. HCl + KOH -> kCl + H2O (b) What is the molar ratio between acid and base...
July 6, 2009 by Lena

Chemistry
How many grams of KNO3 are needed to make 450 mL of a solution that is to contain 5.50 mg/mL of potassium ion? Calculate the molarity of the solution. ______g ______M i honestly don't know where to start, but i know that M=mol/L will be involved somewhere... Please help...
May 10, 2011 by Sam

chemistry
8.058g x 10-2 kg of washing soda na2co3 10h20 is dissolved in water to obtain 1L of a solution of density 1077.2kg/m3. Calculate the molarity, molality and mole fraction of na2c03 in the solution? who helps
January 1, 2013 by Fai

chemistry
Find the molar masses of the following compounds: 1. LiI 2. PbCO4 3. Mg(OH)2 4. (NH4)3PO4 Find the percent composition (percent by mass) of the given element in the following compounds: 1. Fluorine in AgF 2. Hydrogen in glucose (C6H12O6) 3. Oxygen in Fe2(SO4)3 PART II: ...
March 2, 2015 by Alex

Chemistry
What formula do I use to figure. 16.5 g of KCL (MM=74.55 g/mol) is dissolved in enough water to make 575 mL of solution. Calculate the molarity of the KCl solution.
July 25, 2010 by Norma

chemistry urg!
Hydrochloric acid is sold as a concentrated acqueous solution. If the molarity of HCl is 12.0 and its density is 1.18 g/ml. calculate A) MOLALITY B)THE % BY MASS OF HCl in the solution
May 11, 2011 by Daniel Forero

Chemistry
Calculate the molarity of Na2C204 solution prepared by dissolving 1.2222 grams of pure Na2C204 in enough water to make 500.00 mL of solution.
October 25, 2011 by Ashley(please help!!!!)

Chemistry
Calculate the molarity of Na2C204 solution prepared by dissolving 1.2222 grams of pure Na2C204 in enough water to make 500.00 mL of solution.
October 25, 2011 by Ashley(please help!!!!)

science
A solution of NaOH(molar mass 40g mol-1)is prepared by dissolving 1.6g of NaOH in 500 cm cube of water.Calculate molarity(M) of the solution
April 6, 2013 by Divya

chemistry
the density of an aqueous solution containing 10.0% by mass ethanol is 0.984 g/ml. calculate molality and molarity. what volume of the solution would contain 1.15 g ethanol ?
May 4, 2016 by jerry

Chemistry
An aqueous solution is 8.50% ammonium chloride, NH4Cl, by mass. The density of the solution is 1.024g/mL. Calculate the molality, mole fraction, and molarity of NH4Cl in the solution. I know the formulas needed but I'm not sure where to start. M = moles solute/1 L solution m...
January 24, 2012 by S

chemistry
A titration of 15.75mL HCL of an unknown molarity requires 20.35mL of 0.0903M NaOH solution. What is the molarity of the HCl solution?
October 28, 2014 by xx

CHemistry....Please help
What mass of ethylene glycol C2H6O2, the main component of antifreeze, must be added to 10.0 L water to produce a solution for use in a car's radiator that freezes at -23C? Assume density for water is exactly 1g/mL. ----------------------------------- This is what i have so ...
January 22, 2009 by Saira

Chem 104
Molarity of KHP ___ moles/L with a KOH titrant
November 10, 2016 by Hannah Marie

Chemistry
Acetic acid (HOAc) is a weak acid with a Ka= 1.8 X 10^-5 and sodium hydroxide (NaOH) is a strong base. What is the pH of a solution made by mixing 75.0 ml of a 0.160 M solution NaOH and 25.0 ml of a 0.640 M solution of HOAc? I got a pH of 5.22, but I am not sure if this is ...
May 12, 2009 by Chelsea

CHEMISTRY
How can we determine the equivalence point ( or end point ) in the curves in titration ( strong acid/weak base and weak acid/strong base )
September 12, 2014 by MAD

chem
A sample of potassium hydrogen oxalate, KHC204, weighing 0.717 g, was dissolved in water and titrated with 18.47 mL of an NaOH solution. Calculate the molarity of the NaOH solution.
November 21, 2012 by amanda78

difficult chemistry
Calculate the molarity of thiosulfate solution if 0.400mg of Kl03 required 100ml of the thiosulfate solution provided that excess kl and hcl were added. Who helps me
January 12, 2013 by Fai

chemistry
A sample of potassium hydrogen oxalate, KHC2O4, weighing 0.717 g, was dissolved in water and titrated with 18.47 mL of an NaOH solution. Calculate the molarity of the NaOH solution.
April 27, 2015 by mary

chemistry
A 0.0875 M solution of aqueous ammonia was titrated with a solution of sulphuric acid. If 25.00 mL of the ammonia solution required 30.66 mL of the acid to reach the end-point, calculate the molarity of the acid. NH3(aq) + H2SO4(aq) ¨ (NH4)2SO4(aq)
January 10, 2008 by caleb

chemistry
5.85g of sodium chloride is dissolved in 250mL of solution. Calculate: a)the molarity of the solution b)the mass percentage of the solute. can we use the given volume(i.e,250mL as total volume of the solution or volume of water in this problem?
November 3, 2013 by Asmera

chemistry
a solution is made by dissolving 25 g NaCl in enough water to make 1.0 L solution. Assume that density of the solution is 1.0 g/mL. calculate the mass percent, molarity, molality, and mole fraction of NaCl. help please 25g/58.44g NaCl=.428 mol 1000 grams of solvent H20 25g/58,...
January 6, 2015 by an

chemistry
Calculate the molarity of each of the following solutions. 1. 61.9 g of C2H6O in 3.4 L of solution
March 9, 2011 by Abby

chemistry
Calculate the molarity of 2.05 L of a solution containing 1.51 g of dissolved KBr
February 9, 2012 by jessica

general chemistry
Calculate the molarity of each of the following solutions.70.8 in 2.51 of solution
March 7, 2013 by kelia

chemistry
calculate the molarity of 29.25 grams of NaCl in 2.0 liters of solution
May 28, 2013 by Anonymous

chemistry
Can someone make sure that I am correct with my first solution? Also I need help with the 2nd problem. I am a little confused about where to begin. 1.) 1.7423g of potassium dichromate were placed in a 250.00 mL volumetric flask and water was added to the mark. Calculate the ...
October 7, 2008 by titration

chemistry
an aqueous solution solution of sodium borate is sometimes used to to fire-proof wood. a. what is the molarity of 2.50 L of solution that contains 1.85 moles of sodium borate? b. what is the molarity of 45.0 L of solution that contains 6.78 kg of sodium borate? c. how manny ...
April 7, 2013 by Jessica

Chemistry.
Calculate the pH of the resultant solution when 40.00 mL of 0.250 M H2SO4 are mixed with 30.00 mL of 0.450 M KOH. The answer says it is 1.032...I get 12.70 (and I subtract that from 14 I still only get 1.3) Thanks.
May 16, 2009 by Duffy

Chemistry
Calculate the number of milliliters of 0.782 M KOH required to precipitate all of the Mn2+ ions in 112 mL of 0.461 M Mn(NO3)2 solution as Mn(OH)2.
October 16, 2014 by Jessica

chemistry
A sample of the primary standard, Potassium hydrogen phthalate, weighing 0.3589g requires 14.96mL of NaOH solution for neutralization. calculate the molarity of the NaOH solution.
October 21, 2009 by Reen

chemistry
sodium metal dissolves im liquid mercury to form of NA(s) and Hg(l) are 0.97 g/ml and 13.6 g/ml respectively. a sodium amalgoum is made by dissolving 10 ml Na (s) in 20.0 ml Hg (l). The final volume of solution is 21.0 ml. Calculate the molarity of Na in the solution.
January 31, 2013 by masharat

Chemistry
A sample of 30.0 mL of sulfuric acid solution was titrated with 0.720 M KOH. It was found that 46.9 mL of the base was needed to neutralize the acid. What is [H2SO4]? would you do (30.0)(0.720) / 46.9 ?
October 12, 2011 by Hannah

Chemistry
If 20.2 mL of base are required to neutralize 29.3 mL of the acid, what is the molarity of the nitric acid solution?
February 10, 2015 by Rachel

Chemistry
What how can I calculate the amount in moles and the mass in grams of KOH needed to convert 1.50 g of aluminum to KAl(OH)4. Balanced equation = 2 Al (s) + 2 KOH (aq) + 6 H2O (l)->2 KAl(OH)4 (aq) + 3 H2 (g) Please show steps ..
February 29, 2012 by Cynthia

chemistry 101
If 15g of NaOh is dissolved in 285 g of water, calculate the following. Assume the density of the solution is 1.06 g/cc. a) Calculate the moles of NaOH in the solution? My answer is 15gNaOH/40g NaOH= .0375 mole NaOH b) Waht is the mass % w/w of the solution? My answer is 15g ...
December 8, 2012 by Tracy

Chemistry
What is the molarity of Cu2+ in a catalyzed reaction using 3 drops of CuSO4 at .03M in 50.0ml, and what is the molarity of Cu2+ using 6 drops? (Consider the extent of dilution of the 0.1 M CuSO4 solution in preparing the 50 mL reaction solution. Estimate 20 drops/mL.) My Work...
October 3, 2015 by Jim

Chemistry
Imagine that you needed to choose an indicator for the titration of a strong base (like NaOH) with a strong acid (like HNO3). You have the indicators in Table 1 available. Which indicator would you choose? Why? Indicator [HIn] [ In] pKa Maryland Red- Red Blue 4.3 Terrapin ...
September 30, 2012 by Cris

Chemistry
Why is the equivalence point of a weak acid-strong base titration above 7.0? How can the data reflect this? The titration of a weak acid with a srong base produces a salt of the two. The anion is hydrolyzed in water solution but the cation is not. A^- + HOH ==> HA + OH^- ...
April 23, 2007 by Anonymous

Chemistry
Calculate the molarity of the nitrate ion in a 0.111 M solution of calcium nitrate? so would I have to find the number of moles of (NO3)2 and then divide it by the 0.111 M to get the molarity of the nitrate ion I am so confused please explain the set up I don't want the answer...
March 22, 2013 by Amber

molarity
calculate the molarity of k+ in a soln prepared by adding .2L of .200M K3PO4 and 75.0mL of .5M K3PO4. assume volumes are additive. A few of steps here and more than one way to answer the problem You need to calculate the total number of moles of K3PO4 from the two volumes and ...
April 5, 2007 by Christine

Molarity
A 4.0−L sample of a 6.3M NaCl solution is diluted to 50L . What is the molarity of the diluted solution? How would I set this up?
April 19, 2015 by Chemistry

chemistry
When I have the table filled out, what would I need to do in order to calculate the solubility product for calcium hydroxide? The following is what I have in mind, please tell if I am incorrect or correct. Ksp = [Ca+2][OH-1]2 You should have an average value for the amount of ...
April 2, 2008 by Jessica

chemistry
Bit confused about this question. especially a and b. Not really sure which values to use or how. Thanks! A solution is made by dissolving 1.71g of barium hydroxide, Ba(OH)2 (s), in distilled water and then adding more distilled water until the total volume of the solution is ...
November 17, 2009 by Anonymous

chem
Which of the following pairs of substances, when mixed in any proportion you wish, can be used to prepare a buffer solution? (Select all that apply.) NaCN and HCN NaCN and NaOH HCN and NaOH HCl and NaCN HCl and NaOH I thought it was the middle three because each either has a ...
April 10, 2011 by Rebekah

science
Calculate the molarity of 500. mL of solution containing 21.1 g of potassium iodide
October 12, 2010 by kate

Chemistry
Calculate the molarity of a 5.4% sodium hydroxide solution whose density is 1.07 g/mL.
December 6, 2010 by anaymous

chem 150
calculate the molarity of 700grams of NaOH in 2 liters of solution
June 22, 2011 by nick

gp school
calculate the molarity of a solution when 5g of urea is dissolved in 600ml of water
August 20, 2011 by shiksha

chemistry
Calculate the molarity of a 295 mL solution contain 45 g of ethanol (C2H5OH)
November 27, 2011 by jane

Chemistry
Calculate the molarity of a 100. mL solution containing 22.3 g of sucrose (C12H22O11)
September 24, 2012 by Mariah

chemisty 2
Calculate the molarity (M) of a solution if you have 0.34 mol of NaOH in 19 ml of water
October 23, 2012 by chris

college chemistry
Calculate the molarity (M) of 156.2g of H2SO4 in 1.275L of solution.
June 16, 2015 by Alicia Estrada

chemistry
Calculate the molarity of a 6% solution of ammoniun nitrate of density 1.025 g/mL
December 7, 2015 by derek

Chemistry
A 30 mL sample of 0.150 M KOH is titrated with 0.125 M HClO4 solution. Calculate the pH after the following volumes of acid have been added: 30 mL, 35 mL, 36 mL, 37 mL, and 40 mL.
March 8, 2011 by Melissa

Chemistry
A 30 mL sample of 0.150 M KOH is titrated with 0.125 M HClO4 solution. Calculate the pH after the following volumes of acid have been added: 30 mL, 35 mL, 36 mL, 37 mL, and 40 mL.
March 8, 2011 by Melissa

Chemistry-Dr.Bob
Calculate the mass of Fe(OH)3 s) produced by mixing 50.0 mL of 0.153 M KOH (aq) and 25.0 mL of 0.255 M Fe(NO3)3 (aq), and the number of moles of the excess reactant remaining in solution.
November 13, 2015 by Rucha

chemistry
What is the pOH of a 0.032 M Ca(OH)2 (strong base) solution? i solved it by doing 14=-log (0.064) 14-1.19= 12.81 but the right answer is 1.19, why? i thought the OH in the problem meant i had to use 14?
December 11, 2010 by jessie

chemistry
You add thiocynanate ions to a solution The molarity of silver ion is 0.1M initially. Calculate the max concentration of SCN- ion that exists in the solution before AgSCN beings to precipitate? ?
March 15, 2011 by emily

chemistry
Suppose 24.9 grams of copper (II) nitrate is dissolved in 200. milliliters of a 0.70 moles/liter aqueous solution of sodium chromate. Calculate the final molarity of nitrate anion in the solution.
January 20, 2012 by Deborah

Chemistry
Suppose 24.9 grams of copper (II) nitrate is dissolved in 200. milliliters of a 0.70 moles/liter aqueous solution of sodium chromate. Calculate the final molarity of nitrate anion in the solution.
January 20, 2012 by Deborah

Chemistry
3. 25.0 mL of a 0.50 M solution of acid HA was combined with 25.0 mL of a 0.50 solution of base MOH in a calorimeter with a calorimeter constant of 13.5 J/ C. The initial temperature of the solution was 23.3 C and the maximum temperature was 34.7 C. The resulting solution had ...
April 16, 2013 by Kim

CHEMISTRY
1) An NaOH solution of unknown concentration is titrated with HCl. 51.9 mL of 0.400 mol/L HCl will neutralize 75.0 mL of the NaOH. What is the concentration of the NaOH solution ? Record your answer in decimal notation. I think the answer is 0.277 mol/L. is that right? 2)An ...
January 31, 2012 by TIANDRA

chemistry; acids and bases
Since Ka x Kb = Kw, is the conjugate base of a weak acid a weak base or a strong base?
April 26, 2010 by Diem

Chemistry
A 30.0-ml sample of 0.165 M propanoic acid is titrated with 0.300 M KOH. What is the pH at 5 ml of added base, at 10 ml of added base?
March 19, 2013 by Annie

chemistry
A compound was found to be composed of the following amounts of elements: 20.00% wt% C, 26.64wt% O, 46.65 wt%N, and 6.71wt%H. A 6.125 grams sample of this compound dissolved in 46.205 grams of water as a solution was found to have a freezing point of -3.260C. The density of ...
April 25, 2013 by lucy

chemistry: please check work
How many grams of solute are contained in 64.3 mL of 0.0238M KOH? Do I convert 64.3ml to L=.0643L Multiiply .0643L and .0238M KOH=.00153 Multiply .00153 and 56.105 g/mol KOH=.0858g KOH
May 5, 2014 by Suzanne

Chemistry
Calculate the molarity and the molality of an NH3 solution made up of 30 g of NH3 in 70 g of water. The density of the solution is 0.982 g/ml. Molar Mass of NH3 = 17.04 g
December 2, 2010 by Sara

AP Chemistry
A chemist mixes 200.0mL of 0.800 M Fe(NO3)3 and 300.0 mL of 0.750 M K2Cr04 and enough of either 0.400 M KOH or 0.400 M Pb(no3)2 to end up with only two spectator ions in solution. a. How much precipitate will be formed b. How many mL of KOH or Pb(No3)2 must be used c. What are...
January 16, 2011 by qwerty123

Chemistry
Complete this table of initial and final concentrations HF(aq) + KOH(aq) <-> KF(aq) + H20(l) Initial concentrations: HF-2.0M KOH-1.0M KF-0M Final Concentrations? how do I set this up to figure out the final concentrations? How can I tell which of the following best ...
July 16, 2013 by Cat

Chemistry
Exactly 100 mL of 0.14 M nitrous acid (HNO2) are titrated with a 0.14 M NaOH solution. Calculate the pH for the following. (a) the initial solution (b) the point at which 80 mL of the base has been added (c) the equivalence point (d) the point at which 105 mL of the base has ...
March 17, 2012 by Tanya

chemisty
calculate the molarity of a solution with .2 moles of sodim hydroxide dissolved in .5L of water
April 27, 2011 by Anonymous

general chemistry
Calculate the molarity of each of the following solutions.70.8g C2H60 in 2.51L of solution
March 7, 2013 by kelia

gpc
Calculate the molarity of a bleach solution that is 8% by mass (m/v) or 8g/100mL sodium hypochlorite.
March 3, 2014 by samry

Chemistry
calculate the molarity of a NaOH solution that requires 42.55 mL to neutralize 3.53 grams of KHP
April 21, 2016 by Klem

Chemistry
A 30.00mL sample of 0.150M KOH is titrated with 0.125M HClO4 solution. Calculate the pH after the following volumes of acid have been added: 30.0 mL, 35.0 mL, 36.0 mL, 37.0 mL, 40.0 mL
November 17, 2011 by Shana

Chemestry
Calculate the volume of a 0.225 M solution of potassium hydroxide,KOH,required to react with 0.215g of acctic acid,CH,COOH=KCH,COO+H2O.
March 4, 2016 by C'm mulerk

chemistry
If 26.223 mL of potassium permanganate solution is required to titrate 1.041 g of ferrous ammonium sulfate hexahydrate, { FeSO4(NH4)2So46H2O }, calculate the molarity of the KMno4 solution. and the equation the lab gave me was Mn04(-) + 8H(+) + 5Fe(+2) ----> Mn(2+) + 4H2O...
March 11, 2008 by chris

Chemistry
0.400 g of a solid base X(OH)2 was dissolved in 50.0 mL of water. The solution was neutralized with 65.80 mL of 0.150 mol/L HCl. Calculate the molar mass of the base. Do I need to set up a dilution equation? I'm not sure what to do.
December 2, 2015 by Anon

Chemistry
You are asked to prepare 500. mL of a 0.150 M acetate buffer at pH 5.00 using only pure acetic acid, 3.00 M NaOH, and water. Calculate the quantities needed for each of the following steps in the buffer preparation. 1. Add acetic acid to ~400 mL of water in a 500 mL beaker. ...
September 28, 2012 by Kw1h

chemistry
1. An aqueous solution of weak base B of unknown concentration is tritrated with a known concentration of strong acid, HA. (a) Write the balanced chemical equation for this acid-base reaction, identifying the conjugate acid/base pairs. (b) If the base-dissociation constant of ...
April 8, 2011 by Phuong

AP Chemistry
Sulfuric acid (H2SO4) is a very strong diprotic acid. If 0.036 moles of sulfuric acid is mixed with water to make 576 mililiter of solution, what is the molarity of H+?
September 30, 2012 by J. A

Chem molarity
A beaker contains 100 grams of 1.20 M NaCl. If you transfer 50% of the solution to another beaker, what is the molarity of the solution remaining in the first beaker?
March 1, 2011 by Toni Jones

chemistry
A piece of Al weighing 2.7g is titrated with 75 mL of H2SO4 (sp.gr. 1.18 g/mL and 24.7% H2SO4 by mass). After the metal is completely dissolved the solution is dilute to 400mL. Calculate molarity of free H2SO4 in solution.
April 17, 2015 by jaimi

Chemistry
The pH of human blood needs to be between 7.35 and 7.45. You want to prepare a buffer solution that gives a pH of 7.40. You decide to use a sodium phosphate buffer: the acid is H2PO− 4 and the conjugate base is HPO2− 4 . You want the concentration of the acid to be...
April 22, 2016 by Emily

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