Tuesday
September 2, 2014

Posts by LaurenB


Total # Posts: 13

Thermochemistry
The standard enthalpy of formation of n-octane is -249.95 kJ/mol. Compute the amount of heat liberated when 5.24 g of n-octane is burned completely with excess oxygen to form carbon dioxide and liquid water.
December 4, 2011

Thermochemistry
A constant pressure calorimeter having a heat capacity of 60.8 kJ/K is used to measure the energy released from burning a compound in excess oxygen to form CO2(g) and H2O(l). If the enthalpy of combustion of the compound is -2914.0 kJ/mol and the temperature of the calorimeter...
December 4, 2011

Thermochemistry
Suppose 23.6 g of ClF3(g) and 40 g of Li(s) are mixed and allowed to react at atmospheric pressure and 25 C until one of the reactants is used up, producing LiCl(s) and LiF(s). Using the NIST value for the enthalpy of formation of ClF3 (webbook.nist.gov), calculate the ...
December 3, 2011

Thermochemistry
Compute the amount of heat released (absolute value) when 2.3 kg of liquid ethanol is burned in excess oxygen to make carbon dioxide and liquid water.
December 3, 2011

Chemistry
A 1.2 g sample of C-5 H-10 O is burned completely in excess oxygen to yield CO2(g) and H2O(l) at 25 C, releasing 43.52 kJ of energy. What is the enthalpy of formation of C-5 H-10 O?
December 2, 2011

Chemistry
Calculate the volume of natural gas (methane) required to bring 3.9 L of water to a boil. Assume the initial temperature of the water is 39 C, and the methane is at 1 bar and 25 C. Assume that methane is an ideal gas, the specific heat capacity of water to be constant and ...
December 2, 2011

Thermochemistry
Compute the change in temperature when 1.1 g of sodium chloride is dissolved in 200.0 mL of water initially at 28 C. The heat capacity of water is 4.184 J/mL/K. Neglect the heat capacity of the NaCl. Species ΔfH (kJ/mol) NaCl(aq)-407.3 NaCl(s) -411.2
December 2, 2011

Thermochemistry
If a chalice made of pure gold weighing 1.24 kg and initially at 15 C is filled with 100.0 mL of water at 89 C, what is the final equilibrium temperature of the system? The heat capacities of water and gold are 75.29 and 25.42 J/mol/K, respectively.
December 2, 2011

Thermochemistry
A sample of liquid mercury (mass 58 g and temperature 149.0 C) is poured into 79 g of H2O at 19 C. Calculate the final temperature of the mixture, assuming no heat is lost. The heat capacities of Hg and H2O are 27.98 and 75.33 J/mol/K, respectively.
December 2, 2011

ThermoChemistry
Calculate the final temperature of solution when 10 g of oxalic acid, (COOH)2(s), is dissolved in 110.0 mL of water that is initially at 26 C. The enthalpies of formation of oxalic acid in the solid and aqueous phases are -826.8 and -818.8 kJ/mol, respectively. The heat ...
December 2, 2011

ThermoChemistry
If 18 g of Kr initially at 0.5 bar and 18 L is brought to 0.49 bar and 5L, what is the overall change in enthalpy of this process? Assume that Kr is an ideal gas.
December 2, 2011

ThermoChemistry
When 19 mL of water at 22 C is combined with 18 mL of water at 64 C, what is the final temperature of the water?. The specific heat of water is 4.184 J/g/K and its density is 1.0 g/mL.
December 2, 2011

Chemistry
The enthalpy of dissociation for hydrogen H2(g) → 2 H(g) is ΔH = 436.0 kJ/mol. What is the difference between the bond enthalpy (ΔH) and bond energy (ΔE) for this process under standard conditions at 298.15 K?
December 2, 2011

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