Monday
July 28, 2014

Posts by DrBob222


Total # Posts: 43,199

CHEMISTRY
1)If we dissolve 0.03 mols HF in 1L H2O, we have prepared a solution that is 0.03M in HF. However, since HF is a weak acid, it dissociates(partly) in solution to HF + H2O ==> H3O^+ + F^- and the HF present as the molecule is decreased to 0.027M. 2) Any amount of HF in any a...

CHEMISTRY
For the second question and increase in the forward direction increases OH in the HPO4 rxn and that decreases pH. For the CO3^2- rxn the increase in the forward rxn decreases pH because H3O^+ is being used. For the initial post I don't know what you're asking.

math
Would that be 20*21/2 ?

chemistry
[275 mL/(725+275)] x 100 if you want it is %volume.

Science
I don't buy A. For example, I might observe that my clothes are wet and explain by saying I walked home in the rain. However I could have gotten wet by taking a shower with my clothes on. So I don't think just any explanation can go with just any observation.

Chemistry
I think the easy way to do b is to convert everything to millimols and use that to construct an ICE table. I think this way is easier than converting everything to final M. mmols HBz = mL x M = 250 x 0.125 = 31.25 mmols Bz^ = 250 x 0.147 = 36.75 mmols HCl added = 15.3 ...........

Chemistry
Are you sure about part a? I think an error is starting with 0.45M formic acid. Wouldn't you need to start with more formic acid to end up with 0.45M? If you used the HH equation for part b you should have come up with 3.64 and you're a long way from that. I used 3.75 ...

Chemistry
I thought we did all this yesterday. You worked the formula on your own and I showed you how to do the molar mass and molecular formula.

Chemistry
The procedure looks ok but the numbers don't.You must be punching the wrong buttons. The 0.00485 is really 0.004855 and I would round that to 0.00486 M (and that's M and not m) = 0.000198 x 1.92 = 0.000381 and molar mass is 0.242/0.000381 = ? Check my work.

Chemistry
You're right so far. 5.41E6 J = 5.41E3 kJ. molar mass Glauber's salt is 322 so here is what you have. 322 g salt absorbs 74.4 kJ. So how many g will it take to absorb 5.41E3 kJ. That will be 322 x (5.41E3 kJ/74.4 kJ) = ? g of the salt.

Chemistry
q = mass air(in g) x specific heat air x delta T Solve for q (which is delta H) Convert to g of the salt to give that delta H.

Chemistry
Glacial acetic acid is about 17.5M mL1 x %1 = mL2 x %2 mL1 x 17.5 = 120 mL x 25% mL 1 = ?

Chemistry
10% by volume means 10mL ethanol/100 mL solution. You want 150 mL so 10 mL ethanol x (150/100) = ? mL ethanol required.

chemistry
mols NaOH = M x L = ? mols vinegar = mols NaOH M vinegar = mols vinegar/L vinegar = ?

chemistry
You may be thinking that the double bond makes it a trigonal planar structure but when ethylene (with double bonds) is polymerized the double bond is broken and polyethylene consists of single bonds and that makes it tetrahedral. :-)

Chemistry
heat lost by Fe + heat gained by H2O = 0 [mass Fe x specific heat Fe x (Tfinal-Tinitial)] + [mass H2O x specific heat H2O x (Tfinal-Tinitial)] = 0 Substitute the numbers and solve for Tfinal H2O You may need to look up specific heat Fe and H2O if they aren't given in the p...

Chemistry
Nope. Liquid CAN'T be right. If you pour 100 mL water into a 100 mL container it is filled. If you pour the same volume f 100 mL water into a 500 mL container is will NOT be filled. So liquid can't be right. The answer of liquid is NOT using common sense. You KNOW the ...

Chemistry
I really wonder about this science bug with some. Many questions, like this one, is just common sense. Think this through and you'll have the answer. If you pour 100 mL water(a liquid) into a 100 mL beaker will it fill it? Will that same 100 mL water fill a 500 mL containe...

science
http://www.webelements.com/ Scroll down the table to find these elements and compare with the elements above them.

chemistry
mL1 x %1 = mL2 x %2 350 x 15 = mL x 9

Chemistry
121J/c/313 = ? J/g*C

Science
I believe the answer is B. Here is an example of weighing by difference and why it is a good method. Let's assume we know the mass of can accurately as 10g and a tennis ball accurately as 5 g. Now we use a scale in which we can't adjust the zero. Let's suppose at r...

CHEM
I'm assuming that 6.0m is a typo and you meant 6.0M.(There is a difference). mL1 x M1 = mL2 = M2 mL1 x 6.0M = 110 mL x 0.500M

Chemistry
A factor converts any unit to any other unit. The factor used depends upon which unit you have and which unit you want. For example. A. There are 10 mm to 1 cm so the conversion factor is 10mm/1cm or you can write it the other way as 1 cm/10mm. 8.43 cm x factor = ? mm Now we d...

Chemistry
No, if pi = MRT then M = pi/RT M = 0.00543/(0.08205*301) = about 0.000220M or mols/L. M = mols/L mols = M x L = 0.000220*1.37L = about 0.000301 mols = grams/molar mass or molar mass = grams/mols = 0.325/0.000301 = ? Note, however, that even if what you proposed were correct th...

Chemistry
pi = MRT pi = 4.13 torr/760 = ? atm M = unknown R = 0.08205 T = 28 + 273 = ? Solve for M in mols/L You know M and L, solve for mols. Then mol = grams/molar mass. Youj know grams and mols, solve for molar mass. NOTE: In the future it would help if you would show what you know a...

Chemistry
Since the empirical formula mass is about the same as the molecular formula mass then the molecular formula is the same as the empirical formula.

Chemistry
Yes, empirical formula is C3H2N10. Empirical formula mass is 178. (3*12) + (2*1) + (10*14) = 178 The approximate molar mass is given by the boiling point elevation. delta T = Kb*m 1.84 = 2.53*m m = about 0.7 but you need to go through this and all other calculations. I've ...

Chemistry
I don't see a question here.

Chemistry
Then Xunk = mols unk/total mols. 0.2 = [(23.71g/Y)/(23.71Y)+(0.281)] and solve for Y = molar mass unknown. I made a typo in the above. It should be 0.2 = [23.71/Y/(23.71/Y)+ (0.281)]. First the numerator = 0.2*denominator. 23.71/Y = [0.2*(23.71/Y) + (0.281)] 23.71/Y = (4.74/Y)...

Chemistry
pEtBr = XEtBr*PoEtBr 319.7 = X*400 XEtBr = about 0.8 (estimated) see last post. Xunk = 1-about 0.8 = about 0.2 mols unk = 23.71/molar mass or 23.71/Y. mols EtBr = 30.64/109 = about 0.281 Then Xunk = mols unk/total mols. 0.2 = [(23.71g/Y)/(23.71Y)+(0.281)] and solve for Y = mol...

Chemistry
0.218M means 0.218 mols CH3COOH/L solution. g CH3COOH = 0.218 x molar mass = approx 13g but you should redo this and all of the other calculations that follow. I've estimated everything. From density, mass = volume x density = 1000 mL x 1 g/mL = 1000 grams. So 1000g = mass...

CHEMISTRY
delta H is - according to the rxn as written. delta S is - according to the rxn as written If dG is +, then TdS is more + than dH. I guess that means dS is more negative than dH but it's the TdS TERM that counts.

CHEMISTRY
When you ask which direction the rxn will shift I think you must say "if T is added" or "if P is increased" or some other variable is changed. Perhaps you are asking which direction is spontaneous?

CHEMISTRY
See the above about my trouble with the word shift. 1. products higher S than reactants. dS = + 2. reactants higher S than products. dS = - 3. products higher S than reactants. dS = + 4. reactants higher S than products. dS = -

CHEMISTRY
All of this looks good to me except for the last part. Since the number of significant digits is 4 (at least I'm calling 3900 as 4 because I assume it is 3900.) then that 2.99 is really 2.997 ( or if not 4 s.f. for 3900 then it would be 2.997 and round to 3) which makes th...

CHEMISTRY
How much of this do you know how to do. Show your work and let me go through it.

chemistry
The ammonium ion (NH4^+) is hydrolyzed according to this equation. NH4^+ + H2O ==> H3O^+ + NH3 (H3O^+) = acidic

CHEMISTRY
Why do you have the problem identifying the conjugate pairs? The pair consists of the one with more H and the one with less H. And for CO3^2- it should be obvious not to pick H2O as its conjugate pair.

CHEMISTRY
How are we going to do that? Then we have B::N and there are too many electrons around the central atom.

CHEMISTRY
pi = iMRT i is 1 for the four listed so it all depends upon M. Which M gives the largest pi?

chem
heat produced by burning 9.69g C6H6 is 5.69 mJ/mol x (9.69/molar mass C6H6) = ? MJ. Convert to J. Then J = mass H2O in g x specific heat H2O x (Tfinal-Tintial) and solve for Tf.

chem
How much heat was evolved in the combustion? That's 3209.0 kJ/mol x (1.829/159.29) = q = ? Then q = Ccal*delta T. Solve for Ccal.

Chemistry
Assuming you are using an indicator, you stop when the indicator changes color from its acid color to its base color.

Chemistry
That 5.67% m/v means 5.67 g glucose/100 mL blood; therefore, 5.67g glucose x (5,200 mL/100 mL) = ?

Fun time
1.55 g/mL x 3000 mL = ? The mass of the H2SO$ in that 3.0L is 1.55 g/mL x 3000 mL x 0.65 = ?

Chemistry
I agree

Chem 1120
Yes and no. You have Kc given in the problem. All you need to do is to substitute Kc into the Kp = Kc*(RT)^delta n and solve for Kp and you're done. The only thing changing I2 from solid to gas changes is delta n. For I2(g) ==>2I^-(g) delta n will be 2-1 = 1

Chem 1120
Kp = Kc(RT)^delta n. BTW, isn't I2 a solid. Then does I2 go in the denominator.

Chemistry
1___________ 2__________ 3_________ 1__________ Mix the two and you have 3_________ 1___________ 2__________

Chemistry
Yes. If that 1.1 is 1.1 and not 1.10 atm, then 0.71 is right. If it is 1.10 you should have one more place in your answer.

Chemistry
Two points. If T is to 4 places I would use R as 0.08205 although that won't make much difference. The other one makes more difference. P is 1.1 atm in the problem and not 1.

Chemistry
no. If you obtained two different answers why did you pick that one? You know something must be wrong. How did you get V = 24.7 L. If I plug those numbers into V =nRT/P I don't get that. But I do obtain a number that agrees with the formula I gave you.

Chemistry
The general gas formula of PV = nRT can be modified to P*molar mass = density*R*T

Chemistry
n = mols gas = 0.155/22.4 = ? n = grams/molar mass. You know n and grams, solve for molar mass.

Chem
1170.0 kJ/42.75 x #g = 191.9 kJ

Science
Probably not D.

Chemistry
This question makes no sense.

chemistry
and your answer?

Science
And your answer is?

Science
And your answer?

science
When you cut a bar magnet in two you end up with two smaller bar magnets. You don't get a monopole.

science
To get a sonic boom in air the "jet" must travel faster than the speed of sound in air. For air that is about 343 m/s. The "jet" fish would need to travel faster than the speed of sound in water. At 25C the speed of sound in fresh water is about 1497 m/s or...

science
In general, the speed of sound with wind is speed in still air + speed of wind. So shouting with the wind at your back means the speed is increased; shouting with the wind in your face means sound to your front is decreased speed.

babysitting
It doesn't sound like that to me but I'll take your word for it. However, you still listed no choices.

no choices--babysitting
This is baby sitting?

chemestry
E = R(1/n^2 - 1/n^2) R = 1.097E7*(1/4 - 1/25)

exam
CH4 + 2O2 ==> CO2 + 2H2O dHfrxn = (n*dHf products) - (n*dHf reactants) dHf rxn = -780 kJ/mol Substitute the others and solve for dHf CO2

CHEMISTRY
Did I miss something here? If the solubility of KClO3 is 10g/100g H2O and you add 15 g KClO3 to 100 g H2O, then it will dissolve 10 g KClO3 and the other 5g KClO3 will be unaffected. Of course the solution is saturated after the water has dissolved all it can.

CHEMISTRY
What do you mean by embedded. Do you mean you dissolved 15g or you added 15g KClO3.

CHEMISTRY
1. 1% means 1g I2/100 g solution = 10g I2/1000g solution = 10g I2/(10g I2+ 990g ethanol) 2. mol I2 = grams/molar mass 3. m = mols/kg solvent = ? You can convert to M if you know the density of the solution.

chemistry
Will alter the enthalpy of what?

science
http://en.wikipedia.org/wiki/Reflection_%28physics%29

Surds
(a+b)^2 = a^2 + ab + b^2

CHEISTRY
Do you know the order of the reaction?

Chemistry
LiOH(s) + H2O(l) ==> Li^+(aq) + OH^-(aq) dimeNH(l) + H2O(l) ==> dimeNH2^+(aq) + OH^-(aq)

science
What's the Law of Inertia say? That an object in motion tends to stay in motion until acted upon by an outside forcew. The car is traveling at 50 km/hr so the dummy, the car seats, the belts, the steering wheel and everything in the car is also traveling at 50 km/hr. When ...

science
You can read all about "clocks in rocks" here. http://www.sciencecourseware.com/virtualdating/files/1.0_ClocksInRocks.html I shall be happy to critique your summary explanation.

chemistry
C6H12O6 ==> 2C2H5OH + 2CO2 mols glucose = grams/molar mass = estimated 0.5 Using the coefficients in the balanced equation, convert mols glucose to mols ethanol. That is 0.5 x (2 mols ethanol/1 mol glucose) = 0.5 x 2 = 1 mol ethanol produced. Then g ethanol = mols x molar m...

science
mols H2SO4 = grams/molar mass Then M = mols H2SO4/L solution. Note: 100 mL = 0.100 L.

electric circuit
Probably 6 cells in series to give 12 v, then 6 sets of those (36 cells total) in parallel.

Clincal
I don't see a question here.

chemistry
Please read and rephrase. It makes no sense as is.

chemistry
See your other post above.

no image---science

Chemistry
mL1 x M1 = mL2 x M2 mL1 x 17.8 = 250 x 2.00M Add some distilled H2O to the 250 mL volumetric flask, then pipet the value of mL1 of the 17.8M H2SO4 into the 250 mL flask adding concentrated H2SO4 cautiously. Add distilled H2O to the mark and mix thoroughly.

chemistry
1 in^3 = 16.38 cc 13.4 in^3 to cc = ? 1 lb = 453.59 grams 5.14 lb to grams = ? Then d = mass/volume

CHEMISTRY
How much voltage do you need? How much can you get from these two materials? Look up the Eo values and calculate.

CHEMISTRY
Here is a simplified activity series table. A metal will displace any metal ION BELOW it in the activity series; i.e., Al will displace Cu^2+ but Cu will not displace Al^3+. 2Al + 3Cu^2+ ==> 3Cu(s) + 2Al^3+ Cu^2+ + Al^3+ ==> no reaction. http://www.cod.edu/people/faculty...

CHEMISTRY
Look up the standard reduction potentials for I2, Br2, and Al^3+. Then set them up on a sheet of paper something like this, along with H2. ..........................Eo vs SHE Br2 + 2e --> 2Br^-..........1.07 I2 + 2e --> 2I^- ...........0.54 2H^+ + 2e --> H2..............

CHEMISTRY
See the activity series question.

CHEMISTRY
By definition, reduction occurs at the cathode.

CHEMISTRY
You obtain the electrolysis products of H2O and not Al.

CHEMISTRY
It's an arbitrary standard and an arbitrary number.

CHEMISTRY
I wouldn't say they contained H2O but I agree they are moist. Compared to a wet cell; however, relatively speaking the dry cells are dry.

CHEMISTRY
You repeated my line but didn't answer if this was a made up problem or not. I don't like that answer until I have more information about the question.

CHEMISTRY
I wonder if this is a made up problem? Sn^2+ + 2e ==> Sn E = -0.14 Cr --> Cr^3+ + 3e E = ? ---------------------- Ecell = -0.60 then Cr must be -0.46 written as an oxidation so as a reduction it would be +0.46 but that isn't what it gives in the tables.

chemistry
What numbers do you have?

Chemistry
Some picky points. n N2 I obtained 0.007279 so I rounded to 0.00728. For n O2 I obtained 0.00436 I obtained 0.0029 for mols N2 just as you did; however, it is done by 0.0036 x 2/3 and not 3/2. Finally,(this is not so picky) the problem asks for mL so you should convert your 0....

Chemistry
almost. n = 0.0079? Why did you throw away the 1 on 0.00791. You have three places in yur other numbers; you should keep three for the answers. Then if I multiply 0.00791 x 16 I get 0.1265678 which rounded to 3 s.f. is 0.127grams CH4.

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