Once you have calculated your Ka value, use the data to find the concentration of the unknown acids.

Vol. of acid solution=25mL

concentration of NaOH used = 1M

Buffer (pH) = 8.35 at 11.5mL

1/2 11.5=5.75mL which is a pH of 3.58

I did pH=pKa + log(acid/base) to find the pKa

pH=pKa=10^-3.58

Ka=2.63x10^-4

I don't understand what you've done but the HH equation should be pH = pKa + log (base)/(acid).

After you know the Ka value, assuming it is monoprotic, then
mLacid x Macid = mLbase x Mbase

To find the concentration of the unknown acid using the Ka value, you can use the Henderson-Hasselbalch equation:

pH = pKa + log([acid]/[base])

Here, [acid] refers to the concentration of the acid and [base] refers to the concentration of the conjugate base of the acid. Since you know the Ka value (2.63x10^-4) and the pH (8.35), you can rearrange the Henderson-Hasselbalch equation to solve for [acid]:

[acid] = 10^(pH - pKa)

Plugging in the values:

[acid] = 10^(8.35 - (-3.58))

[acid] = 10^(11.93)

[acid] = 1.59 x 10^11

Therefore, the concentration of the unknown acid is approximately 1.59 x 10^11 M.