Posted by Chris on Sunday, March 3, 2013 at 1:35pm.
I looked at this yesterday and nothing jumped out at me for A.
B you can do several ways. Perhaps the easiest is to calculate how much CO2 is produced by each. (or you could use H2O if you wish).
mol = grams/molar mass.
convert mols product to mols CO2
Convert mols CO2 to g. g = mols x molar mass.
For C8H8O3
2C8H8O3 + 17O2 ==>16CO2 x 8H2O
mols vanillin = 1.00g/152 = 0.00658
0.00658 x (16 mols CO2/2 mol C8H8O3) = 0.00658 x (16/2) = 0.0526 g CO2. Can't be it; CO2 was 1.54g. Try the sugar.
C12H22O11 + 12O2 ==> 12CO2 + 11H2O
mol = 1/342 = 0.00292
0.00292 x (12 mol CO2/1 mol C12H22O11) = 0.00292 x 12 = 0.0350
0.0350 mol x 44 = 1.54g. Must be this one.
C. The equations are written in B.
D. As for D I don't know to what data they refer. But you know the answer. Mass WAS conserved so they must have been confusing their numbers.
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