Posted by Hannah on Tuesday, July 17, 2012 at 4:17pm.
What happens is that the Na of Na2SO4 (many products use NaCl instead of Na2SO4) to replace the Ca, Mg, and other ions such as Fe. In simple fashion, if we let the resin be x, then
NaX + Ca^+2 ==> CaX2 + 2Na^+.
Mg and Fe would look the same.
Here is a Wikepedia article you can read if you need more information.
http://en.wikipedia.org/wiki/Water_softening
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