February 1, 2015

Homework Help: Chemistry

Posted by Sara on Sunday, February 27, 2011 at 8:17pm.

Please check my answers.

1. Using the equations,
IO3- +5I- + 6H+ -> 3I2 + 3H2O
C6H8O6 + I2 -> C6H6O6 + 2I- + 2H+

how many equivalents of IO3- are required to produce enough I2 to oxidize one equivalent of ascorbic acid?

Answer: 1IO3- <-> 3I2 <-> 3C6H8O6
1/3 equivalents of IO3-

2. A 10 g sample of no name grape drink mix is diluted to 250 mL. 50 mL of grape drink is titrated with 35 mL of 0.005 M KIO3 solution.

a) How many moles of ascorbic acid are present in 50 mL of the grape solution?

0.005 mol/L KIO3 x 0.035 L KIO3 =
1.75 x 10^-4 mol KIO3

1.75 x 10^-4 mol KIO3 x (3 mol I2/1 mol KIO3) = 5.25 x 10^-4 mol I2.

3 KIO3 <-> 3 C6H8O6, so same amount of moles of C6H8O6.

b) What is the percent by mass of ascorbic acid in a package of grape drink mix?

5.25 x 10^-4 mol C6H8O6 x 176.124 g/mol C6H8O6 = 0.092 g C6H8O6

But this is grams in 50 mL of solution - we have 250 mL throughout which the ascorbic acid is distributed. So 0.092 g x 5 = 0.462 g C6H8O6 within 250 mL solution.

0.462 g/10.00 g x 100 = 4.62%

c) If there are 8 servings per package, calculate the %RDA of vitamin C in each serving of no name grape mix. Formula: (mg ascorbic acid/serving)/75 mg

(462 mg C6H8O6/8)/75 mg
= 0.77 % RDA

Thanks for your help!

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