Posted by flame on Thursday, November 11, 2010 at 2:14am.
The NH3 doesn't replace the Cl-. AgCl is not very soluble. The AgCl that does dissolve solvates with water forming in solution Ag(H2O)2+ and Cl-. (the 2 is a subscript) The NH3 coordinates more strongly than water, so the NH3 replaces the coordinated water. The compound that actually forms is Ag(NH3)2Cl. (again, the 2 is a subscript)
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