Posted by Anonymous on Thursday, November 4, 2010 at 10:32am.
Calculate the pH of a 0.5 M Formic Acid (HCOOH) soln. ka= 0.00018

College Chemistry  bobpursley, Thursday, November 4, 2010 at 10:52am
Ka=[H][COOH]/([HCOOH]
ka= x^2/(.5x)
solve this for x
x^2+.00018x.5*.00018=0
x=(.00018+sqrt(.00018^2+.00036))/2
x=.00009+ .00948= .00939 check all that math.
pH=log (.00939)=2.03
check the math.

College Chemistry  Dr Russ, Thursday, November 4, 2010 at 10:52am
The equilibrium is given by
HCOOH > H+ + HCOO
so Ka=[H+][HCOO]/[HCOOH]
if we start with 0.5M HCOOH then at equilibrium there is [H+] = x and [HCOO]=x and HCOOH=0.5x
so Ka = (x)(x)/(0.5x)=0.00018
this gives a quadratic to solve, however, we only want the answer to 1 sig fig (.5M is 1 sig fig) so we can say that 0.5x is approximately equal to 0.5, because x will be small.
thus x^2/0.5=0.00018
hence you can find x
pH is then log(x)
which is pH=2, but check the maths.
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