what pH values can be assigned to acids and bases respectively?

Any numbers; however, I suspect you are asking which pH values show acid and which show base.

pH = 7 is neutral.
pH<7 = acid
pH>7 = base.

To determine the pH values that can be assigned to acids and bases, let's start with the pH scale. The pH scale measures the acidity or basicity of a substance and ranges from 0 to 14.

Acids have a pH value below 7. The lower the pH value of an acid, the stronger the acidity. For example, a strong acid like hydrochloric acid (HCl) has a pH value close to 0, while a weak acid like vinegar (acetic acid, CH3COOH) may have a pH value around 3-4.

Bases, also known as alkaline substances, have a pH value above 7. The higher the pH value of a base, the stronger the basicity. For instance, a strong base like sodium hydroxide (NaOH) has a pH value close to 14, while a weak base like baking soda (sodium bicarbonate, NaHCO3) may have a pH value around 8-9.

It's important to note that there are also neutral substances with a pH value of 7, such as pure water. These substances are neither acidic nor basic.

To determine the pH value of an acid or base experimentally, you can use pH paper or a pH meter. pH paper changes color depending on the acidity or basicity of a solution, allowing you to estimate the pH value. A pH meter, on the other hand, provides a more precise measurement by directly measuring the concentration of hydrogen ions (H+) in a solution.