Posted by Kristin on Wednesday, April 14, 2010 at 1:49pm.
1. The TOTAL OH should be determined from moles HCl used in the titration. The HCl can't tell the difference between NaOH OH and Ca(OH)2 OH and you obtain total OH with this titration.
2. You know how much OH is there due to NaOH from its concn and volume added.
3. Thus, the Ca^+2 is the difference between the two with an adjustment made for Ca being 1/2 of OH of Ca(OH)2.
4.Ksp for Ca(OH)2 is then (Ca^+2)(OH^-)^2
5. The solubility of Ca(OH)2 in NaOH is just the (Ca^+2).
Check my thinking.
Ok, so for the first one I got mol of HCl=4.92x10^-4 and so [OH-] is 4.92x10^-4/.020L = .0246 mol/L. Is that correct?
And then from there I have the [OH-] in NaOH to be (.0125)(.020L) = 2.5x10^-4
[OH-] in Ca(OH)2 is .0246-2.5x10^-4 = .02435
[Ca2+] then is .012175
Are my calculations correct?
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